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Click chemistry strategies for the accelerated synthesis of functional macromolecules
Click chemistry is one of the most powerful strategies for constructing polymeric soft
materials with precise control over architecture and functionality. In this review, we provide a …
materials with precise control over architecture and functionality. In this review, we provide a …
Thiol–ene click chemistry
CE Hoyle, CN Bowman - Angewandte Chemie International …, 2010 - Wiley Online Library
Following Sharpless′ visionary characterization of several idealized reactions as click
reactions, the materials science and synthetic chemistry communities have pursued …
reactions, the materials science and synthetic chemistry communities have pursued …
50th Anniversary Perspective: Polymer Functionalization
The translation of small molecule chemistries into efficient methodologies for polymer
functionalization spans several decades, enabling critical advances in soft matter materials …
functionalization spans several decades, enabling critical advances in soft matter materials …
The thiol-Michael addition click reaction: a powerful and widely used tool in materials chemistry
The key attribute of the thiol-Michael addition reaction that makes it a prized tool in materials
science is its modular “click” nature, which allows for the implementation of this highly …
science is its modular “click” nature, which allows for the implementation of this highly …
Thiol-click chemistry: a multifaceted toolbox for small molecule and polymer synthesis
The merits of thiol-click chemistry and its potential for making new forays into chemical
synthesis and materials applications are described. Since thiols react to high yields under …
synthesis and materials applications are described. Since thiols react to high yields under …
Thiol-ene “click” reactions and recent applications in polymer and materials synthesis
AB Lowe - Polymer Chemistry, 2010 - pubs.rsc.org
This review highlights examples of recent applications of both the radical-mediated and
base/nucleophile-initiated thiol-ene reactions in polymer and materials synthesis. Initial …
base/nucleophile-initiated thiol-ene reactions in polymer and materials synthesis. Initial …
Alginate modification via click chemistry for biomedical applications
Alginate biopolymers are characterized by favorable properties, of biocompatibility,
degradability, and non-toxicity. However, the poor stability properties of alginate have limited …
degradability, and non-toxicity. However, the poor stability properties of alginate have limited …
Diels–Alder “click” reactions: recent applications in polymer and material science
MA Tasdelen - Polymer Chemistry, 2011 - pubs.rsc.org
The “click” chemistry concept is based on utilizing rapid reactions which are efficient,
versatile, and selective. Indeed, Diels–Alder (DA) reactions fulfill most of the requirements …
versatile, and selective. Indeed, Diels–Alder (DA) reactions fulfill most of the requirements …
Bioapplications of RAFT polymerization
A living radical polymerization (LRP) is a free radical polymerization that aims at displaying
living character,(ie, does not terminate or transfer and is able to continue polymerization …
living character,(ie, does not terminate or transfer and is able to continue polymerization …
Thiol–maleimide “click” chemistry: evaluating the influence of solvent, initiator, and thiol on the reaction mechanism, kinetics, and selectivity
BH Northrop, SH Frayne, U Choudhary - Polymer Chemistry, 2015 - pubs.rsc.org
The mechanism and kinetics of thiol–maleimide “click” reactions carried out under a variety
of conditions have been investigated computationally and using experimental competition …
of conditions have been investigated computationally and using experimental competition …