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Mild metal-catalyzed C–H activation: examples and concepts
Organic reactions that involve the direct functionalization of non-activated C–H bonds
represent an attractive class of transformations which maximize atom-and step-economy …
represent an attractive class of transformations which maximize atom-and step-economy …
C− H functionalisation for hydrogen isotope exchange
J Atzrodt, V Derdau, WJ Kerr… - Angewandte Chemie …, 2018 - Wiley Online Library
The various applications of hydrogen isotopes (deuterium, D, and tritium, T) in the physical
and life sciences demand a range of methods for their installation in an array of molecular …
and life sciences demand a range of methods for their installation in an array of molecular …
Exploiting hexafluoroisopropanol (HFIP) in Lewis and Brønsted acid-catalyzed reactions
Hexafluoroisopropanol (HFIP) is a solvent with unique properties that has recently gained
attention for promoting a wide range of challenging chemical reactions. It was initially …
attention for promoting a wide range of challenging chemical reactions. It was initially …
Computational studies of carboxylate-assisted C–H activation and functionalization at group 8–10 transition metal centers
Computational studies on carboxylate-assisted C–H activation and functionalization at
group 8–10 transition metal centers are reviewed. This Review is organized by metal and …
group 8–10 transition metal centers are reviewed. This Review is organized by metal and …
Lewis superacids: classifications, candidates, and applications
Lewis acids play a major role in all areas of chemistry. For a long time, toxic, corrosive and
oxidizing SbF5 was considered as the strongest Lewis acid known. Lately, species …
oxidizing SbF5 was considered as the strongest Lewis acid known. Lately, species …
Platinum-catalyzed C–H functionalization
JA Labinger - Chemical Reviews, 2017 - ACS Publications
Recent developments in C–H bond activation and functionalization by Pt complexes are
surveyed. Topics include the following: fundamental mechanistic investigations of C–H …
surveyed. Topics include the following: fundamental mechanistic investigations of C–H …
Palladium-catalyzed nondirected late-stage C–H deuteration of arenes
We describe a palladium-catalyzed nondirected late-stage deuteration of arenes. Key
aspects include the use of D2O as a convenient and easily available deuterium source and …
aspects include the use of D2O as a convenient and easily available deuterium source and …
Deuteration and Tritiation of Pharmaceuticals by Non‐Directed Palladium‐Catalyzed C− H Activation in Heavy and Super‐Heavy Water
Deuterated and tritiated analogs of drugs are valuable compounds for pharmaceutical and
medicinal chemistry. In this work, we present a novel hydrogen isotope exchange reaction of …
medicinal chemistry. In this work, we present a novel hydrogen isotope exchange reaction of …
New trends in oxidative functionalization of carbon–hydrogen bonds: A review
GB Shul'pin - Catalysts, 2016 - mdpi.com
This review describes new reactions catalyzed by recently discovered types of metal
complexes and catalytic systems (catalyst+ co-catalyst). Works of recent years (mainly 2010 …
complexes and catalytic systems (catalyst+ co-catalyst). Works of recent years (mainly 2010 …
The power of the proton: from superacidic media to superelectrophile catalysis
Superacidic media became famous in connection with carbocations. Yet not all reactive
intermediates can be generated, characterized, and eventually isolated from these Brønsted …
intermediates can be generated, characterized, and eventually isolated from these Brønsted …