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The Nitrogen Bond, or the Nitrogen-Centered Pnictogen Bond: The Covalently Bound Nitrogen Atom in Molecular Entities and Crystals as a Pnictogen Bond Donor
The nitrogen bond in chemical systems occurs when there is evidence of a net attractive
interaction between the electrophilic region associated with a covalently or coordinately …
interaction between the electrophilic region associated with a covalently or coordinately …
Definition of the Halogen Bond (IUPAC Recommendations 2013): A Revisit
This Article revisits the “Definition of the Halogen Bond (IUPAC Recommendations
2013)”[Desiraju, GR Pure Appl. Chem. 2013, 85 (8), 1711–1713], recommendations that fail …
2013)”[Desiraju, GR Pure Appl. Chem. 2013, 85 (8), 1711–1713], recommendations that fail …
The halogen bond with isocyano carbon reduces isocyanide odor
Predominantly, carbon atoms of various species function as acceptors of noncovalent
interactions when they are part of a π-system. Here, we report on the discovery of a halogen …
interactions when they are part of a π-system. Here, we report on the discovery of a halogen …
Recognition of the π-hole donor ability of iodopentafluorobenzene–a conventional σ-hole donor for crystal engineering involving halogen bonding
Iodopentafluorobenzene (IPFB or PhFI) was co-crystallized with tetra (n-butyl) ammonium
tetraiodo-μ, μ′-diiododiplatinate (II),[n-Bu4N] 2 [Pt2 (μ-I2) I4](1), to give the adduct 1· 2IPFB …
tetraiodo-μ, μ′-diiododiplatinate (II),[n-Bu4N] 2 [Pt2 (μ-I2) I4](1), to give the adduct 1· 2IPFB …
Biosolar oxygenation of hydrocarbons by photocatalytic artificial wood
Lignin is the most abundant renewable and sustainable source of aromatic compounds to
replace fossil resources, causing environmental issues. However, most lignin generated …
replace fossil resources, causing environmental issues. However, most lignin generated …
Enhanced solubility and bioavailability of clotrimazole in aqueous solutions with hydrophobized hyperbranched polyglycidol for improved antifungal activity
The poor solubility of clotrimazole in the aqueous medium and the uncontrolled removal of
the drug-loaded suppository content limit its effectiveness in the treatment of vulvovaginal …
the drug-loaded suppository content limit its effectiveness in the treatment of vulvovaginal …
Counterion Variation: A Useful Lever for Maximizing the Regioselectivity in the Hydroboration of Terminal Alkynes
A Martínez-Bascuñana, JL Núñez-Rico, L Carreras… - ACS …, 2023 - ACS Publications
The role of the counterion in metal-catalyzed reactions can be crucial as this often-
unconsidered component of the catalyst can modify the performance of the catalyst and …
unconsidered component of the catalyst can modify the performance of the catalyst and …
One-Pot Route to X-perfluoroarenes (X = Br, I) Based on FeIII-Assisted C–F Functionalization and Utilization of These Arenes as Building Blocks for Crystal …
Perfluorinated arenes (benzeneF derivatives, diphenylF, naphthaleneF) were converted into
X-perfluoroarenes (X= Br, I) via the developed one-pot protocol based on [Fe …
X-perfluoroarenes (X= Br, I) via the developed one-pot protocol based on [Fe …
A halogen bond-donor amino acid for organocatalysis in water
Herein we report a halogen bond-donor amino acid, 4-iodotetrafluorophenylalanine, which
behaves as a catalyst for the aqueous synthesis of bis-(heterocyclic) methanes. We also …
behaves as a catalyst for the aqueous synthesis of bis-(heterocyclic) methanes. We also …
Direct investigation of chalcogen bonds by multinuclear solid-state magnetic resonance and vibrational spectroscopy
We report a multifaceted experimental and computational study of three self-complementary
chalcogen-bond donors as well as a series of seven chalcogen bonded cocrystals. Bis …
chalcogen-bond donors as well as a series of seven chalcogen bonded cocrystals. Bis …