[BOOK][B] Scorpionates: the coordination chemistry of polypyrazolylborate ligands
S Trofimenko - 1999 - books.google.com
This book deals with polypyrazolylborates (scorpionates), a class of ligands known since
1966, but becoming rapidly popular with inorganic, organometallic and coordination …
1966, but becoming rapidly popular with inorganic, organometallic and coordination …
An Actinide Complex with a Nucleophilic Allenylidene Ligand
O Ordoñez, X Yu, MA Schuerlein, G Wu… - Journal of the …, 2024 - ACS Publications
The reaction of [Cp3Th (3, 3-diphenylcyclopropenyl)](Cp= η5-C5H5) with 1 equiv of lithium
diisopropylamide (LDA) results in cyclopropenyl ring opening and formation of the thorium …
diisopropylamide (LDA) results in cyclopropenyl ring opening and formation of the thorium …
Rhodium-catalyzed dimerization of terminal alkynes assisted by MeI
CC Lee, YC Lin, YH Liu, Y Wang - Organometallics, 2005 - ACS Publications
Dimerization of terminal arylalkynes at ambient temperature catalyzed by Rh (CO)(PPh3)
2Cl (2) in the presence of MeI leads to formation of enyne with high conversion and high …
2Cl (2) in the presence of MeI leads to formation of enyne with high conversion and high …
Preparation, Characterization, and Reactivity of Azido Complex Containing a Tp(tBuNC)(PPh3)Ru Fragment and Ruthenium-Catalyzed Cycloaddition of Organic …
YH Lo, TH Wang, CY Lee, YH Feng - Organometallics, 2012 - ACS Publications
Treatment of the TpRu complex (PPh3)[Ru]-Cl (1,[Ru]= Tp (t BuNC) Ru) with an excess of
sodium azide affords the yellow ruthenium azido complex (PPh3)[Ru]-N3 (2). The triazolato …
sodium azide affords the yellow ruthenium azido complex (PPh3)[Ru]-N3 (2). The triazolato …
Neutral ruthenium carbene complexes bearing N, N, O heteroscorpionate ligands: syntheses and activity in metathesis reactions
H Kopf, B Holzberger, C Pietraszuk, E Hübner… - …, 2008 - ACS Publications
Neutral Fischer-type ruthenium (II) aminocarbene complexes bearing the bis (3, 5-
dimethylpyrazol-1-yl) acetato (bdmpza) ligand have been synthesized by addition of …
dimethylpyrazol-1-yl) acetato (bdmpza) ligand have been synthesized by addition of …
C− H Bond Activation of Terminal Allenes: Formation of Hydride-Alkenylcarbyne-Osmium and Disubstituted Vinylidene-Ruthenium Derivatives
A Collado, MA Esteruelas, F López… - …, 2010 - ACS Publications
The reactivity of the dihydrides MH2Cl2 (PiPr3) 2 (M= Os (1), Ru (2)) toward allenes has
been studied. Complex 1 reacts with 2 equiv of 3-methyl-1, 2-butadiene and 1-methyl-1 …
been studied. Complex 1 reacts with 2 equiv of 3-methyl-1, 2-butadiene and 1-methyl-1 …
Tripodal N, N, O-ligands for metalloenzyme models and organometallics
N Burzlaff - Advances in Inorganic Chemistry; Academic Press …, 2008 - books.google.com
The number of known or presumed mononuclear, non-heme iron oxygenases and related
enzymes continues to grow. This is due to intensive biochemical research and especially …
enzymes continues to grow. This is due to intensive biochemical research and especially …
Exploitation of a chemically non-innocent acetate ligand in the synthesis and reactivity of ruthenium vinylidene complexes
Reaction of the ruthenium bis-acetate complex cis-Ru (κ2-OAc) 2 (PPh3) 2 with a range of
terminal alkynes HC CR (R= Ph, CO2Me, C {OH} Ph2, C {OH} Me2) results in the formation …
terminal alkynes HC CR (R= Ph, CO2Me, C {OH} Ph2, C {OH} Me2) results in the formation …
Octahedral Ru(II) Amido Complexes TpRu(L)(L')(NHR) (Tp = Hydridotris(pyrazolyl)borate; L = L' = P(OMe)3 or PMe3 or L = CO and L' = PPh3; R = H, Ph, or tBu) …
D Conner, KN Jayaprakash, MB Wells… - Inorganic …, 2003 - ACS Publications
The octahedral Ru (II) amine complexes [TpRu (L)(L ')(NH2R)][OTf](L= L '= PMe3, P (OMe) 3
or L= CO and L '= PPh3; R= H or tBu) have been synthesized and characterized …
or L= CO and L '= PPh3; R= H or tBu) have been synthesized and characterized …
The organometallic chemistry of group 8 Tris (pyrazolyl) borate complexes
E Becker, S Pavlik, K Kirchner - Advances in Organometallic Chemistry, 2008 - Elsevier
Publisher Summary This chapter describes the organometallic aspects of tris
(pyrazolylborate) anion (Tp) chemistry of the group 8 metals—that is, the synthesis …
(pyrazolylborate) anion (Tp) chemistry of the group 8 metals—that is, the synthesis …