Star polymers

JM Ren, TG McKenzie, Q Fu, EHH Wong, J Xu… - Chemical …, 2016 - ACS Publications
Recent advances in controlled/living polymerization techniques and highly efficient coupling
chemistries have enabled the facile synthesis of complex polymer architectures with …

[HTML][HTML] Copper-mediated living radical polymerization (atom transfer radical polymerization and copper (0) mediated polymerization): from fundamentals to …

C Boyer, NA Corrigan, K Jung, D Nguyen… - Chemical …, 2016 - ACS Publications
The discovery of the first “living” radical polymerization by Otsu and co-workers (1) in 1982
heralded the start of a very exciting time for polymer chemists. Since then, a plethora of living …

Cu (0)-mediated living radical polymerization: a versatile tool for materials synthesis

A Anastasaki, V Nikolaou, G Nurumbetov… - Chemical …, 2016 - ACS Publications
During the past decade we have witnessed the rapid development and understanding of
living radical polymerization (LRP)(or reversible deactivation radical polymerizations …

Kinetics of atom transfer radical polymerization

P Krys, K Matyjaszewski - European Polymer Journal, 2017 - Elsevier
This review encompasses the fundamentals of kinetics of atom transfer radical
polymerization (ATRP). ATRP is a versatile reversible-deactivation radical polymerization …

Reversible-deactivation radical polymerization in the presence of metallic copper. A critical assessment of the SARA ATRP and SET-LRP mechanisms

D Konkolewicz, Y Wang, M Zhong, P Krys… - …, 2013 - ACS Publications
Reversible-deactivation radical polymerization (RDRP) in the presence of Cu0 is a versatile
technique that can be used to create well-controlled polymers with complex architectures …

Exploitation of the degenerative transfer mechanism in RAFT polymerization for synthesis of polymer of high livingness at full monomer conversion

G Gody, T Maschmeyer, PB Zetterlund… - Macromolecules, 2014 - ACS Publications
We report the synthesis by the reversible addition–fragmentation chain transfer process of
well-defined decablock polymers with a final dispersity as low as 1.15 and a fraction of living …

Cu (0)-mediated living radical polymerization: recent highlights and applications; a perspective

A Anastasaki, V Nikolaou, DM Haddleton - Polymer Chemistry, 2016 - pubs.rsc.org
Cu (0)-mediated living radical polymerization or single electron transfer living radical
polymerization (Cu (0)-mediated LRP or SET-LRP) is a versatile polymerization technique …

Organic nanoparticles with tunable size and rigidity by hyperbranching and cross-linking using microemulsion ATRP

R Yin, J Tarnsangpradit, A Gul, J Jeong, X Hu… - Proceedings of the …, 2024 - pnas.org
Unlike inorganic nanoparticles, organic nanoparticles (oNPs) offer the advantage of “interior
tailorability,” thereby enabling the controlled variation of physicochemical characteristics and …

High molecular weight block copolymers by sequential monomer addition via Cu (0)-mediated living radical polymerization (SET-LRP): an optimized approach

A Anastasaki, C Waldron, P Wilson, C Boyer… - ACS Macro …, 2013 - ACS Publications
The synthesis of well-defined high molecular weight block copolymers by sequential in situ
chain extensions via Cu (0)-mediated living radical polymerization is reported. Optimal …

Analysis of the Cu (0)-catalyzed polymerization of methyl acrylate in disproportionating and nondisproportionating solvents

NH Nguyen, ME Levere, J Kulis, MJ Monteiro… - …, 2012 - ACS Publications
The kinetic and structural analyses of the polymer resulting from the Cu (0)/Me6-TREN-
mediated polymerization of methyl acrylate (MA) initiated with methyl 2-bromopropionate …