This article surveys the empirical information which originated both by laboratory
experiments and by computational simulations, and expands previous understanding of the …

Ultracold molecules offer unprecedented opportunities for the controlled interrogation of
molecular events, including chemical reactivity in the ultimate quantum regime. The …

Abstract The prototypical F+ H 2→ HF+ H reaction possesses a substantial energetic barrier
(~ 800 K) and might therefore be expected to slow to a negligible rate at low temperatures. It …

To account for frequently documented low-temperature deviations from Arrhenius rate law,
the proposed expansion of inverse activation energy against inverse temperature is shown …

The OH+ HBr→ H2O+ Br reaction, prototypical of halogen-atom liberating processes
relevant to mechanisms for atmospheric ozone destruction, attracted frequent attention of …

Bistable multifunctional materials have great potential in a large variety of devices, from
sensors to information units. However, the direct exploitation of spin crossover (SCO) …

A formulation is presented for the application of tools from quantum chemistry and transition‐
state theory to phenomenologically cover cases where reaction rates deviate from Arrhenius …

The Transitivity function, defined in terms of the reciprocal of the apparent activation energy,
measures the propensity for a reaction to proceed and can provide a tool for implementing …

Integral cross sections and rate constants for the prototypical chemical reactions of the
fluorine atom with molecular hydrogen and deuterium have been calculated over a wide …

Among four-atom processes, the reaction OH+ HBr→ H2O+ Br is one of the most studied
experimentally: its kinetics has manifested an unusual anti-Arrhenius behavior, namely, a …