Three-and four-coordinate gold (I) complexes

MC Gimeno, A Laguna - Chemical reviews, 1997 - ACS Publications
Gold is a very special element; it has been known and cherished since the earliest
civilizations. It has occupied an important place in the history of mankind for over 7000 years …

Metal complexes with non-innocent ligands

KP Butin, EK Beloglazkina, NV Zyk - Russian chemical reviews, 2005 - iopscience.iop.org
The review summarises data on transition metal complexes with the so-called non-innocent
ligands. The specific feature of these complexes is that the oxidation state of the central …

Molecular aggregation of annular dinuclear gold (I) compounds containing bridging diphosphine and dithiolate ligands

SS Tang, CP Chang, IJB Lin, LS Liou… - Inorganic …, 1997 - ACS Publications
A series of annular dinuclear Au (I) complexes containing diphosphine (R2P (CH2) n PR2;
R= Me, n= 1, dmpm; R= Me, n= 2, dmpe; R= Ph, n= 1, dppm; R= Ph, n= 2, dppe) and …

Synthesis, characterization, and in vitro cytotoxicity of some gold (I) and trans platinum (II) thionate complexes containing water-soluble PTA and DAPTA ligands. X-ray …

S Miranda, E Vergara, F Mohr, D de Vos… - Inorganic …, 2008 - ACS Publications
A series of gold (I) and platinum (II) complexes of the type [Au (SR)(P)] and trans-[Pt (SR) 2
(P) 2][SR= 2-thiopyridine (SPy), 2-thiopyrimidine (SPyrim); P= 1, 3, 5-triaza-7 …

Structures and structural trends in homoleptic dithiolene complexes

CL Beswick, JM Schulman… - … Synthesis, Properties, and …, 2003 - Wiley Online Library
This article reviews structural aspects of over 500 homoleptic dithiolene complexes
characterized by X‐ray diffraction. Topics such as structural geometries, ligand types, and …

Do S,S'-Coordinated o-Dithiobenzosemiquinonate(1−) Radicals Exist in Coordination Compounds? The [AuIII(1,2-C6H4S2)2]1-/0 Couple

K Ray, T Weyhermüller, A Goossens… - Inorganic …, 2003 - ACS Publications
The square planar, light-green, diamagnetic complex [N (n-Bu) 4][AuIII (L t-Bu) 2](1) reacts
with iodine in acetone affording the neutral paramagnetic species [Au (L t-Bu) 2](1a)(S= 1/2) …

The chemistry of gold

MC Gimeno - … Gold Chemistry: Gole-Metal Interactions and …, 2008 - Wiley Online Library
Gold was discovered as shining yellow nuggets and is undoubtedly the first metal known to
early civilizations. The symbol derives from the Latin word aurum, which is related to the …

Gold (I) complexes of P, N ligands and their catalytic activity

C Khin, ASK Hashmi, F Rominger - 2010 - Wiley Online Library
Gold (I) complexes were readily prepared by reaction of the respective ligands with (Me2S)
AuCl in CH2Cl2. Complexes of formula LAuCl {L= diphenyl (2‐pyridyl) phosphane …

Metallosupramolecular Structures Derived from a Series of Diphosphine‐bridged Digold(I) Metalloligands with Terminal d‐Penicillamine

N Yoshinari, T Konno - The Chemical Record, 2016 - Wiley Online Library
In this report, we describe our recent work on the development of a new family of chiral
heteroleptic digold (I) metalloligands with mixed diphosphine and d‐penicillaminate (d …

Substitution Reaction Studies on [Au2Cl2(μ-dppf)] (dppf = 1,1'-Bis(diphenylphosphino)ferrocene). Synthesis of the First Gold(I) Complex with a μ3-2-Pyridinethiolate …

F Canales, MC Gimeno, PG Jones, A Laguna… - Inorganic …, 1997 - ACS Publications
Substitution of the chlorine ligand in the complex [Au2Cl2 (μ-dppf)] by other halogens or
anionic ligands such as Spy-(2-pyridinethiolate) or S2CNR2-have been carried out. The …