Recent advances in single molecule magnetism of dysprosium-metallofullerenes
This article outlines the magnetic properties of single molecule magnets based on Dy-
encapsulating endohedral metallofullerenes. The factors that govern these properties, such …
encapsulating endohedral metallofullerenes. The factors that govern these properties, such …
Recent developments of diazo compounds in organic synthesis
D Qiu, J Wang - 2021 - World Scientific
Diazo compounds are versatile organic compounds and have become increasingly
important in organic synthesis and many other fields. In particular, α-diazocarbonyl …
important in organic synthesis and many other fields. In particular, α-diazocarbonyl …
Magic-size II–VI nanoclusters as synthons for flat colloidal nanocrystals
Five new, discretely sized, magic-size II–VI nanoclusters are synthesized in primary-amine
bilayer templates and are isolated as the derivatives [(CdS) 34 (n-butylamine) 18],[(ZnS) 34 …
bilayer templates and are isolated as the derivatives [(CdS) 34 (n-butylamine) 18],[(ZnS) 34 …
Endohedral Metallofullerenes: An Ideal Platform of Sub‐Nano Chemistry
Comprehensive Summary The hollow cavity of fullerenes is an ideal host for the stabilization
of a variety of otherwise unstable metallic clusters, enabling the discovery of novel …
of a variety of otherwise unstable metallic clusters, enabling the discovery of novel …
Dearomative Ring‐Fused Azafulleroids and Carbazole‐Derived Metallofullerenes: Reactivity Dictated by Encapsulation in a Fullerene Cage
Herein, we report divergent additions of 2, 2′‐diazidobiphenyls to C60 and Sc3N@ Ih‐
C80. In stark contrast to that of the previously reported bis‐azide additions, the unexpected …
C80. In stark contrast to that of the previously reported bis‐azide additions, the unexpected …
Lu2@C2n (2n = 82, 84, 86): Crystallographic Evidence of Direct Lu–Lu Bonding between Two Divalent Lutetium Ions Inside Fullerene Cages
Although most of the M2C2 n-type metallofullerenes (EMFs) tend to form carbide cluster
EMFs, we report herein that Lu-containing EMFs Lu2C2 n (2 n= 82, 84, 86) are actually …
EMFs, we report herein that Lu-containing EMFs Lu2C2 n (2 n= 82, 84, 86) are actually …
Biomedical applications of metal‐encapsulated fullerene nanoparticles
The carbonaceous nanomaterials known as metallofullerenes have attracted considerable
attention due to their attractive properties. The robust nature of the “Trojan Horse” fullerene …
attention due to their attractive properties. The robust nature of the “Trojan Horse” fullerene …
Exohedral functionalization of endohedral metallofullerenes: Interplay between inside and outside
Endohedral metallofullerenes (EMFs) are fullerene cages enclosing various metallic
species. The functionalization of EMFs has remarkably blossomed in recent years, in …
species. The functionalization of EMFs has remarkably blossomed in recent years, in …
Crystallographic Evidence for Direct Metal–Metal Bonding in a Stable Open‐Shell La2@Ih‐C80 Derivative
Endohedral metallofullerenes (EMFs) have novel structures and properties that are closely
associated with the internal metallic species. Benzyl radical additions have been previously …
associated with the internal metallic species. Benzyl radical additions have been previously …
Advances in Regioselective Functionalization of Endohedral Metallofullerenes†
Comprehensive Summary Endohedral metallofullerenes (EMFs) are a family of molecules
with metal clusters or ions encapsulated inside a fullerene cage. Their unique structures …
with metal clusters or ions encapsulated inside a fullerene cage. Their unique structures …