Metalation of metal–organic frameworks: fundamentals and applications

HY Li, XJ Kong, SD Han, J Pang, T He… - Chemical Society …, 2024 - pubs.rsc.org
Metalation of metal–organic frameworks (MOFs) has been developed as a prominent
strategy for materials functionalization for pore chemistry modulation and property …

Metal–organic framework (MOF)-, covalent-organic framework (COF)-, and porous-organic polymers (POP)-catalyzed selective C–H bond activation and …

S Daliran, AR Oveisi, Y Peng… - Chemical Society …, 2022 - pubs.rsc.org
Although C–H functionalization is one of the simplest reactions, it requires the use of highly
active and selective catalysts. Recently, C–H-active transformations using porous materials …

MOF-enabled confinement and related effects for chemical catalyst presentation and utilization

J Liu, TA Goetjen, Q Wang, JG Knapp… - Chemical Society …, 2022 - pubs.rsc.org
A defining characteristic of nearly all catalytically functional MOFs is uniform, molecular-
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …

Metal–organic framework-based catalysts with single metal sites

YS Wei, M Zhang, R Zou, Q Xu - Chemical reviews, 2020 - ACS Publications
Metal–organic frameworks (MOFs) are a class of distinctive porous crystalline materials
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …

Principles of design and synthesis of metal derivatives from MOFs

T De Villenoisy, X Zheng, V Wong… - Advanced …, 2023 - Wiley Online Library
Materials derived from metal–organic frameworks (MOFs) have demonstrated exceptional
structural variety and complexity and can be synthesized using low‐cost scalable methods …

Chemical reactivity under nanoconfinement

AB Grommet, M Feller, R Klajn - Nature nanotechnology, 2020 - nature.com
Confining molecules can fundamentally change their chemical and physical properties.
Confinement effects are considered instrumental at various stages of the origins of life, and …

Engineering the coordination sphere of isolated active sites to explore the intrinsic activity in single-atom catalysts

X Wu, H Zhang, S Zuo, J Dong, Y Li, J Zhang, Y Han - Nano-micro letters, 2021 - Springer
Reducing the dimensions of metallic nanoparticles to isolated, single atom has attracted
considerable attention in heterogeneous catalysis, because it significantly improves atomic …

PdCu nanoalloy decorated photocatalysts for efficient and selective oxidative coupling of methane in flow reactors

X Li, C Wang, J Yang, Y Xu, Y Yang, J Yu… - Nature …, 2023 - nature.com
Methane activation by photocatalysis is one of the promising sustainable technologies for
chemical synthesis. However, the current efficiency and stability of the process are …

Neighboring Zn–Zr Sites in a Metal–Organic Framework for CO2 Hydrogenation

J Zhang, B An, Z Li, Y Cao, Y Dai, W Wang… - Journal of the …, 2021 - ACS Publications
ZrZnO x is active in catalyzing carbon dioxide (CO2) hydrogenation to methanol (MeOH) via
a synergy between ZnO x and ZrO x. Here we report the construction of Zn2+–O–Zr4+ sites …

[HTML][HTML] Mixed component metal-organic frameworks: Heterogeneity and complexity at the service of application performances

M Viciano-Chumillas, X Liu, A Leyva-Pérez… - Coordination Chemistry …, 2022 - Elsevier
The synthesis of mixed-component metal-organic frameworks (MOFs)–including multivariate
MOFs (MTV-MOFs), multicomponent MOFs, mixed-metals MOFs and mixed-ligands and …