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Metalation of metal–organic frameworks: fundamentals and applications
Metalation of metal–organic frameworks (MOFs) has been developed as a prominent
strategy for materials functionalization for pore chemistry modulation and property …
strategy for materials functionalization for pore chemistry modulation and property …
Metal–organic framework (MOF)-, covalent-organic framework (COF)-, and porous-organic polymers (POP)-catalyzed selective C–H bond activation and …
Although C–H functionalization is one of the simplest reactions, it requires the use of highly
active and selective catalysts. Recently, C–H-active transformations using porous materials …
active and selective catalysts. Recently, C–H-active transformations using porous materials …
MOF-enabled confinement and related effects for chemical catalyst presentation and utilization
A defining characteristic of nearly all catalytically functional MOFs is uniform, molecular-
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …
Metal–organic framework-based catalysts with single metal sites
Metal–organic frameworks (MOFs) are a class of distinctive porous crystalline materials
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …
Principles of design and synthesis of metal derivatives from MOFs
Materials derived from metal–organic frameworks (MOFs) have demonstrated exceptional
structural variety and complexity and can be synthesized using low‐cost scalable methods …
structural variety and complexity and can be synthesized using low‐cost scalable methods …
Chemical reactivity under nanoconfinement
Confining molecules can fundamentally change their chemical and physical properties.
Confinement effects are considered instrumental at various stages of the origins of life, and …
Confinement effects are considered instrumental at various stages of the origins of life, and …
Engineering the coordination sphere of isolated active sites to explore the intrinsic activity in single-atom catalysts
Reducing the dimensions of metallic nanoparticles to isolated, single atom has attracted
considerable attention in heterogeneous catalysis, because it significantly improves atomic …
considerable attention in heterogeneous catalysis, because it significantly improves atomic …
PdCu nanoalloy decorated photocatalysts for efficient and selective oxidative coupling of methane in flow reactors
Methane activation by photocatalysis is one of the promising sustainable technologies for
chemical synthesis. However, the current efficiency and stability of the process are …
chemical synthesis. However, the current efficiency and stability of the process are …
Neighboring Zn–Zr Sites in a Metal–Organic Framework for CO2 Hydrogenation
ZrZnO x is active in catalyzing carbon dioxide (CO2) hydrogenation to methanol (MeOH) via
a synergy between ZnO x and ZrO x. Here we report the construction of Zn2+–O–Zr4+ sites …
a synergy between ZnO x and ZrO x. Here we report the construction of Zn2+–O–Zr4+ sites …
[HTML][HTML] Mixed component metal-organic frameworks: Heterogeneity and complexity at the service of application performances
The synthesis of mixed-component metal-organic frameworks (MOFs)–including multivariate
MOFs (MTV-MOFs), multicomponent MOFs, mixed-metals MOFs and mixed-ligands and …
MOFs (MTV-MOFs), multicomponent MOFs, mixed-metals MOFs and mixed-ligands and …