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Finding fluorine: photoproduct formation during the photolysis of fluorinated pesticides
The photolysis of pesticides with different fluorine motifs was evaluated to quantify the
formation of fluorinated products in buffered aqueous systems, advanced oxidation (AOP) …
formation of fluorinated products in buffered aqueous systems, advanced oxidation (AOP) …
Wavelength-dependent UV-LED photolysis of fluorinated pesticides and pharmaceuticals
The wavelength dependence of photoproduct formation and quantum yields was evaluated
for fluorinated pesticides and pharmaceuticals using UV-light emitting diodes (LEDs) with …
for fluorinated pesticides and pharmaceuticals using UV-light emitting diodes (LEDs) with …
Electrochemical C–F bond activation of trifluoromethylarenes using silylium ions
S Mondal, B Stevanovic, E Butler, JW Wang… - Chemical …, 2023 - pubs.rsc.org
We report a mild, electrochemical trihydrodefluorination (e-THDF) for breaking highly stable
C–F bonds in trifluoromethyl arenes to form the corresponding methyl arene products …
C–F bonds in trifluoromethyl arenes to form the corresponding methyl arene products …
Using 19F NMR to Investigate Cationic Carbon Dot Association with Per- and Polyfluoroalkyl Substances (PFAS)
There is much concern about per-and polyfluoroalkyl substances (PFAS) based on their
environmental persistence and toxicity, resulting in an urgent need for remediation …
environmental persistence and toxicity, resulting in an urgent need for remediation …
Fluorinated Pharmaceutical and Pesticide Photolysis: Investigating Reactivity and Identifying Fluorinated Products by Combining Computational Chemistry,19F NMR …
Fluorinated breakdown products from photolysis of pharmaceuticals and pesticides are of
environmental concern due to their potential persistence and toxicity. While mass …
environmental concern due to their potential persistence and toxicity. While mass …
Promoted Raney Ni catalyzed hydrodefluorination of fluorophenols under mild conditions via controlling solvents and bases
H Li, X Gong, T Li, S Liu, Y Liu, X Ma, Q Li… - Chemical Engineering …, 2023 - Elsevier
Fluorinated organic compounds (FOCs) are difficult to degrade and persistent in the
environment due to the strong Csingle bondF bond strength. In this context, the applicability …
environment due to the strong Csingle bondF bond strength. In this context, the applicability …
Photolysis products of fluorinated pharmaceuticals: A combined fluorine nuclear magnetic resonance spectroscopy and mass spectrometry approach
The aqueous photolysis of four pharmaceuticals with varying fluorinated functional groups
was assessed under neutral, alkaline, advanced oxidation, and advanced reduction …
was assessed under neutral, alkaline, advanced oxidation, and advanced reduction …
Photochemical Formation of Trifluoroacetic Acid: Mechanistic Insights into a Fluoxetine-Related Aryl-CF3 Compound
Trifluoroacetic acid (TFA) is a ubiquitous environmental contaminant; however, its sources
are poorly constrained. One understudied source is from the photochemical reactions of …
are poorly constrained. One understudied source is from the photochemical reactions of …
Fluorous Liquids for Magnetic Resonance-Based Thermometry with Enhanced Responsiveness and Environmental Degradation
Accurate temperature measurement via magnetic resonance is valuable for both in vitro and
in vivo analysis of local tissue for evaluating disease pathology and medical interventions …
in vivo analysis of local tissue for evaluating disease pathology and medical interventions …
An inventory of fluorspar production, industrial use, and emissions of trifluoroacetic acid (TFA) in the period 1930 to 1999
AA Lindley - Journal of Geoscience and Environment Protection, 2023 - scirp.org
There is a generally accepted conclusion that trifluoroacetic acid (TFA) does occur naturally,
in part based on the large quantities of TFA in the oceans (61-205 million tonnes, measured …
in part based on the large quantities of TFA in the oceans (61-205 million tonnes, measured …