Multimetallic catalysis based on heterometallic complexes and clusters

P Buchwalter, J Rosé, P Braunstein - Chemical reviews, 2015 - ACS Publications
Multimetallic catalysis is based on the combined action of different metals in a chemical
transformation. It has witnessed rapidly increasing developments during the past decades in …

Paramagnetic metal–metal bonded heterometallic complexes

JA Chipman, JF Berry - Chemical reviews, 2020 - ACS Publications
Significant progress has been made in the past 10–15 years on the design, synthesis, and
properties of multimetallic coordination complexes with heterometallic metal–metal bonds …

Restraining the octahedron collapse in lithium and manganese rich NCM cathode toward suppressing structure transformation

Z Xu, X Guo, JZ Wang, Y Yuan, Q Sun… - Advanced Energy …, 2022 - Wiley Online Library
Lithium and manganese rich nickel cobalt manganese oxide (LMRNCM), as an attractive
high energy density cathode for advanced lithium‐ion batteries (LIBs), suffers from inevitable …

Metal–metal (MM) bond distances and bond orders in binuclear metal complexes of the first row transition metals titanium through zinc

RH Duncan Lyngdoh, HF Schaefer III… - Chemical reviews, 2018 - ACS Publications
This survey of metal–metal (MM) bond distances in binuclear complexes of the first row 3d-
block elements reviews experimental and computational research on a wide range of such …

Configuring bonds between first-row transition metals

RJ Eisenhart, LJ Clouston, CC Lu - Accounts of Chemical …, 2015 - ACS Publications
Conspectus Alfred Werner, who pioneered the field of coordination chemistry, envisioned
coordination complexes as a single, transition metal atom at the epicenter of a vast ligand …

Dinuclear nickel complexes in five states of oxidation using a redox-active ligand

YY Zhou, DR Hartline, TJ Steiman, PE Fanwick… - Inorganic …, 2014 - ACS Publications
Redox-active nitrogen donor ligands have exhibited broad utility in stabilizing transition
metal complexes in unusual formal oxidation states and enabling multielectron redox …

Spectroscopic and electrochemical characterization of a Pr 4+ imidophosphorane complex and the redox chemistry of Nd 3+ and Dy 3+ complexes

NT Rice, IA Popov, RK Carlson, SM Greer… - Dalton …, 2022 - pubs.rsc.org
The molecular tetravalent oxidation state for praseodymium is observed in solution via
oxidation of the anionic trivalent precursor [K][Pr3+ (NP (1, 2-bis-tBu-diamidoethane)(NEt2)) …

Installing heterobimetallic cobalt–aluminum single sites on a metal organic framework support

AB Thompson, DR Pahls, V Bernales… - Chemistry of …, 2016 - ACS Publications
A heterobimetallic cobalt–aluminum complex was immobilized onto the metal organic
framework NU-1000 using a simple solution-based deposition procedure. Characterization …

Accessing a synthetic Fe III Mn IV core to model biological heterobimetallic active sites

JL Lee, S Biswas, JW Ziller, EL Bominaar… - Chemical …, 2024 - pubs.rsc.org
Metalloproteins with dinuclear cores are known to bind and activate dioxygen, with a
subclass of these proteins having active sites containing FeMn cofactors and activities …

Origin of Fast Catalysis in Allylic Amination Reactions Catalyzed by Pd–Ti Heterobimetallic Complexes

WK Walker, BM Kay, SA Michaelis… - Journal of the …, 2015 - ACS Publications
Experiments and density functional calculations were used to quantify the impact of the Pd–
Ti interaction in the cationic heterobimetallic Cl2Ti (N t BuPPh2) 2Pd (η3-methallyl) catalyst …