Multimetallic catalysis based on heterometallic complexes and clusters
P Buchwalter, J Rosé, P Braunstein - Chemical reviews, 2015 - ACS Publications
Multimetallic catalysis is based on the combined action of different metals in a chemical
transformation. It has witnessed rapidly increasing developments during the past decades in …
transformation. It has witnessed rapidly increasing developments during the past decades in …
Paramagnetic metal–metal bonded heterometallic complexes
JA Chipman, JF Berry - Chemical reviews, 2020 - ACS Publications
Significant progress has been made in the past 10–15 years on the design, synthesis, and
properties of multimetallic coordination complexes with heterometallic metal–metal bonds …
properties of multimetallic coordination complexes with heterometallic metal–metal bonds …
Restraining the octahedron collapse in lithium and manganese rich NCM cathode toward suppressing structure transformation
Lithium and manganese rich nickel cobalt manganese oxide (LMRNCM), as an attractive
high energy density cathode for advanced lithium‐ion batteries (LIBs), suffers from inevitable …
high energy density cathode for advanced lithium‐ion batteries (LIBs), suffers from inevitable …
Metal–metal (MM) bond distances and bond orders in binuclear metal complexes of the first row transition metals titanium through zinc
RH Duncan Lyngdoh, HF Schaefer III… - Chemical reviews, 2018 - ACS Publications
This survey of metal–metal (MM) bond distances in binuclear complexes of the first row 3d-
block elements reviews experimental and computational research on a wide range of such …
block elements reviews experimental and computational research on a wide range of such …
Configuring bonds between first-row transition metals
Conspectus Alfred Werner, who pioneered the field of coordination chemistry, envisioned
coordination complexes as a single, transition metal atom at the epicenter of a vast ligand …
coordination complexes as a single, transition metal atom at the epicenter of a vast ligand …
Dinuclear nickel complexes in five states of oxidation using a redox-active ligand
YY Zhou, DR Hartline, TJ Steiman, PE Fanwick… - Inorganic …, 2014 - ACS Publications
Redox-active nitrogen donor ligands have exhibited broad utility in stabilizing transition
metal complexes in unusual formal oxidation states and enabling multielectron redox …
metal complexes in unusual formal oxidation states and enabling multielectron redox …
Spectroscopic and electrochemical characterization of a Pr 4+ imidophosphorane complex and the redox chemistry of Nd 3+ and Dy 3+ complexes
The molecular tetravalent oxidation state for praseodymium is observed in solution via
oxidation of the anionic trivalent precursor [K][Pr3+ (NP (1, 2-bis-tBu-diamidoethane)(NEt2)) …
oxidation of the anionic trivalent precursor [K][Pr3+ (NP (1, 2-bis-tBu-diamidoethane)(NEt2)) …
Installing heterobimetallic cobalt–aluminum single sites on a metal organic framework support
A heterobimetallic cobalt–aluminum complex was immobilized onto the metal organic
framework NU-1000 using a simple solution-based deposition procedure. Characterization …
framework NU-1000 using a simple solution-based deposition procedure. Characterization …
Accessing a synthetic Fe III Mn IV core to model biological heterobimetallic active sites
Metalloproteins with dinuclear cores are known to bind and activate dioxygen, with a
subclass of these proteins having active sites containing FeMn cofactors and activities …
subclass of these proteins having active sites containing FeMn cofactors and activities …
Origin of Fast Catalysis in Allylic Amination Reactions Catalyzed by Pd–Ti Heterobimetallic Complexes
WK Walker, BM Kay, SA Michaelis… - Journal of the …, 2015 - ACS Publications
Experiments and density functional calculations were used to quantify the impact of the Pd–
Ti interaction in the cationic heterobimetallic Cl2Ti (N t BuPPh2) 2Pd (η3-methallyl) catalyst …
Ti interaction in the cationic heterobimetallic Cl2Ti (N t BuPPh2) 2Pd (η3-methallyl) catalyst …