Hydrogen spillover. Facts and fiction

R Prins - Chemical reviews, 2012 - ACS Publications
1. INTRODUCTION In 1964, Khoobiar reported that WO3 is reduced by H2 to blue WO3− x
when it is in contact with a Pt catalyst. 1 The blue color appears because hydrogen atoms …

Tuning product selectivity in CO 2 hydrogenation over metal-based catalysts

LX Wang, L Wang, FS **ao - Chemical Science, 2021 - pubs.rsc.org
Conversion of CO2 into chemicals is a promising strategy for CO2 utilization, but its intricate
transformation pathways and insufficient product selectivity still pose challenges. Exploiting …

Interfacial compatibility critically controls Ru/TiO2 metal-support interaction modes in CO2 hydrogenation

J Zhou, Z Gao, G **ang, T Zhai, Z Liu, W Zhao… - Nature …, 2022 - nature.com
Supports can widely affect or even dominate the catalytic activity, selectivity, and stability of
metal nanoparticles through various metal-support interactions (MSIs). However, underlying …

Low-Temperature CO2 Methanation over CeO2-Supported Ru Single Atoms, Nanoclusters, and Nanoparticles Competitively Tuned by Strong Metal–Support …

Y Guo, S Mei, K Yuan, DJ Wang, HC Liu, CH Yan… - ACS …, 2018 - ACS Publications
CO2 hydrogenation for the acquisition of value-added chemicals is an economical means to
deal with the CO2-relevant environmental problems, among which CO2 reduction to CH4 is …

Catalyst support effects on hydrogen spillover

W Karim, C Spreafico, A Kleibert, J Gobrecht… - Nature, 2017 - nature.com
Hydrogen spillover is the surface migration of activated hydrogen atoms from a metal
catalyst particle, on which they are generated, onto the catalyst support. The phenomenon …

Dynamic evolution of palladium single atoms on anatase titania support determines the reverse water–gas shift activity

L Chen, SI Allec, MT Nguyen, L Kovarik… - Journal of the …, 2023 - ACS Publications
Research interest in single-atom catalysts (SACs) has been continuously increasing.
However, the lack of understanding of the dynamic behaviors of SACs during applications …

Controlling CO2 Hydrogenation Selectivity by Metal‐Supported Electron Transfer

X Li, J Lin, L Li, Y Huang, X Pan… - Angewandte Chemie …, 2020 - Wiley Online Library
Tuning CO2 hydrogenation selectivity to obtain targeted value‐added chemicals and fuels
has attracted increasing attention. However, a fundamental understanding of the way to …

Hot Electrons Do the Impossible: Plasmon-Induced Dissociation of H2 on Au

S Mukherjee, F Libisch, N Large, O Neumann… - Nano …, 2013 - ACS Publications
Heterogeneous catalysis is of paramount importance in chemistry and energy applications.
Catalysts that couple light energy into chemical reactions in a directed, orbital-specific …

Enhanced photocatalytic alkane production from fatty acid decarboxylation via inhibition of radical oligomerization

Z Huang, Z Zhao, C Zhang, J Lu, H Liu, N Luo… - Nature Catalysis, 2020 - nature.com
The decarboxylation of bio-derived fatty acids provides a sustainable pathway for the
production of alkane products under mild conditions; however, products are generally …

Hydrogen stabilization of metallic vanadium dioxide in single-crystal nanobeams

J Wei, H Ji, W Guo, AH Nevidomskyy… - Nature …, 2012 - nature.com
Vanadium dioxide is a strongly correlated material,,, that undergoes a metal–insulator
transition from a high-temperature, rutile metal to a monoclinic insulating state at 67° C. In …