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Hydrogen spillover. Facts and fiction
R Prins - Chemical reviews, 2012 - ACS Publications
1. INTRODUCTION In 1964, Khoobiar reported that WO3 is reduced by H2 to blue WO3− x
when it is in contact with a Pt catalyst. 1 The blue color appears because hydrogen atoms …
when it is in contact with a Pt catalyst. 1 The blue color appears because hydrogen atoms …
Tuning product selectivity in CO 2 hydrogenation over metal-based catalysts
LX Wang, L Wang, FS **ao - Chemical Science, 2021 - pubs.rsc.org
Conversion of CO2 into chemicals is a promising strategy for CO2 utilization, but its intricate
transformation pathways and insufficient product selectivity still pose challenges. Exploiting …
transformation pathways and insufficient product selectivity still pose challenges. Exploiting …
Interfacial compatibility critically controls Ru/TiO2 metal-support interaction modes in CO2 hydrogenation
Supports can widely affect or even dominate the catalytic activity, selectivity, and stability of
metal nanoparticles through various metal-support interactions (MSIs). However, underlying …
metal nanoparticles through various metal-support interactions (MSIs). However, underlying …
Low-Temperature CO2 Methanation over CeO2-Supported Ru Single Atoms, Nanoclusters, and Nanoparticles Competitively Tuned by Strong Metal–Support …
CO2 hydrogenation for the acquisition of value-added chemicals is an economical means to
deal with the CO2-relevant environmental problems, among which CO2 reduction to CH4 is …
deal with the CO2-relevant environmental problems, among which CO2 reduction to CH4 is …
Catalyst support effects on hydrogen spillover
W Karim, C Spreafico, A Kleibert, J Gobrecht… - Nature, 2017 - nature.com
Hydrogen spillover is the surface migration of activated hydrogen atoms from a metal
catalyst particle, on which they are generated, onto the catalyst support. The phenomenon …
catalyst particle, on which they are generated, onto the catalyst support. The phenomenon …
Dynamic evolution of palladium single atoms on anatase titania support determines the reverse water–gas shift activity
Research interest in single-atom catalysts (SACs) has been continuously increasing.
However, the lack of understanding of the dynamic behaviors of SACs during applications …
However, the lack of understanding of the dynamic behaviors of SACs during applications …
Controlling CO2 Hydrogenation Selectivity by Metal‐Supported Electron Transfer
X Li, J Lin, L Li, Y Huang, X Pan… - Angewandte Chemie …, 2020 - Wiley Online Library
Tuning CO2 hydrogenation selectivity to obtain targeted value‐added chemicals and fuels
has attracted increasing attention. However, a fundamental understanding of the way to …
has attracted increasing attention. However, a fundamental understanding of the way to …
Hot Electrons Do the Impossible: Plasmon-Induced Dissociation of H2 on Au
Heterogeneous catalysis is of paramount importance in chemistry and energy applications.
Catalysts that couple light energy into chemical reactions in a directed, orbital-specific …
Catalysts that couple light energy into chemical reactions in a directed, orbital-specific …
Enhanced photocatalytic alkane production from fatty acid decarboxylation via inhibition of radical oligomerization
The decarboxylation of bio-derived fatty acids provides a sustainable pathway for the
production of alkane products under mild conditions; however, products are generally …
production of alkane products under mild conditions; however, products are generally …
Hydrogen stabilization of metallic vanadium dioxide in single-crystal nanobeams
Vanadium dioxide is a strongly correlated material,,, that undergoes a metal–insulator
transition from a high-temperature, rutile metal to a monoclinic insulating state at 67° C. In …
transition from a high-temperature, rutile metal to a monoclinic insulating state at 67° C. In …