Molecular chemistry in cavity strong coupling

K Hirai, JA Hutchison, H Uji-i - Chemical Reviews, 2023 - ACS Publications
The coherent exchange of energy between materials and optical fields leads to strong light–
matter interactions and so-called polaritonic states with intriguing properties, halfway …

Molecular polaritonics: Chemical dynamics under strong light–matter coupling

TE Li, B Cui, JE Subotnik, A Nitzan - Annual review of physical …, 2022 - annualreviews.org
Chemical manifestations of strong light–matter coupling have recently been a subject of
intense experimental and theoretical studies. Here we review the present status of this field …

Chemistry under vibrational strong coupling

K Nagarajan, A Thomas… - Journal of the American …, 2021 - ACS Publications
Over the past decade, the possibility of manipulating chemistry and material properties using
hybrid light–matter states has stimulated considerable interest. Hybrid light–matter states …

RETRACTED: Solvent polarity under vibrational strong coupling

M Piejko, B Patrahau, K Joseph, C Muller… - Journal of the …, 2023 - ACS Publications
Vibrational strong coupling (VSC) occurs when molecular vibrations hybridize with the
modes of an optical cavity, an interaction mediated by vacuum fluctuations. VSC has been …

Direct observation of polaritonic chemistry by nuclear magnetic resonance spectroscopy

B Patrahau, M Piejko, RJ Mayer… - Angewandte Chemie …, 2024 - Wiley Online Library
Polaritonic chemistry is emerging as a powerful approach to modifying the properties and
reactivity of molecules and materials. However, probing how the electronics and dynamics of …

Molecular polaritons for chemistry, photonics and quantum technologies

B **ang, W **ong - Chemical Reviews, 2024 - ACS Publications
Molecular polaritons are quasiparticles resulting from the hybridization between molecular
and photonic modes. These composite entities, bearing characteristics inherited from both …

Metal–dielectric interfacial engineering with mesoporous nano-carbon florets for 1000-fold fluorescence enhancements: smartphone-enabled visual detection of …

S Bhaskar, D Thacharakkal… - ACS Sustainable …, 2022 - ACS Publications
Metallic nanosystems with strong surface plasmon resonance have been a predominant
choice for surface plasmon-coupled emission (SPCE), leading to a plethora of sensing and …

Collective strong coupling modifies aggregation and solvation

M Castagnola, TS Haugland, E Ronca… - The Journal of …, 2024 - ACS Publications
Intermolecular (Coulombic) interactions are pivotal for aggregation, solvation, and
crystallization. We demonstrate that the collective strong coupling of several molecules to a …

Analytical evaluation of ground state gradients in quantum electrodynamics coupled cluster theory

MT Lexander, S Angelico, EF Kjønstad… - Journal of Chemical …, 2024 - ACS Publications
Analytical gradients of potential energy surfaces play a central role in quantum chemistry,
allowing for molecular geometry optimizations and molecular dynamics simulations. In …

Non‐Polaritonic Effects in Cavity‐Modified Photochemistry

PA Thomas, WJ Tan, VG Kravets… - Advanced …, 2024 - Wiley Online Library
Strong coupling of molecules to vacuum fields is widely reported to lead to modified
chemical properties such as reaction rates. However, some recent attempts to reproduce …