The many flavours of mechanochemistry and its plausible conceptual underpinnings
Mechanochemistry describes diverse phenomena in which mechanical load affects
chemical reactivity. The fuzziness of this definition means that it includes processes as …
chemical reactivity. The fuzziness of this definition means that it includes processes as …
The role of polymer mechanochemistry in responsive materials and additive manufacturing
The use of mechanical forces to chemically transform polymers dates back decades. In
recent years, the use of mechanochemistry to direct constructive transformations in polymers …
recent years, the use of mechanochemistry to direct constructive transformations in polymers …
Covalent mechanochemistry and contemporary polymer network chemistry: a marriage in the making
Over the past 20 years, the field of polymer mechanochemistry has amassed a toolbox of
mechanophores that translate mechanical energy into a variety of functional responses …
mechanophores that translate mechanical energy into a variety of functional responses …
Validation of the CoGEF method as a predictive tool for polymer mechanochemistry
The development of force-responsive molecules called mechanophores is a central
component of the field of polymer mechanochemistry. Mechanophores enable the design …
component of the field of polymer mechanochemistry. Mechanophores enable the design …
Insights into the Correlation of Microscopic Motions of [c2]Daisy Chains with Macroscopic Mechanical Performance for Mechanically Interlocked Networks
Mimicking filament sliding in sarcomeres using artificial molecular muscles such as [c 2]
daisy chains has aroused increasing interest in develo** advanced polymeric materials …
daisy chains has aroused increasing interest in develo** advanced polymeric materials …
Mechanically responsive luminescent polymers based on supramolecular cyclophane mechanophores
A new approach to cyclophane-based supramolecular mechanophores is presented. We
report a mechanically responsive cyclic motif that contains two fluorescent 1, 6-bis …
report a mechanically responsive cyclic motif that contains two fluorescent 1, 6-bis …
Rotaxane-based dual function mechanophores exhibiting reversible and irreversible responses
T Muramatsu, Y Okado, H Traeger… - Journal of the …, 2021 - ACS Publications
Mechanochromic mechanophores permit the design of polymers that indicate mechanical
events through optical signals. Here we report rotaxane-based supramolecular …
events through optical signals. Here we report rotaxane-based supramolecular …
The rise and promise of molecular nanotopology
Molecular nanotopology—a term we coined recently—is a rapidly develo** field of
research that is emerging out of the confluence of chemical topology with the mechanical …
research that is emerging out of the confluence of chemical topology with the mechanical …
Conformer Ring Flip Enhances Mechanochromic Performance of ansa-Donor–Acceptor–Donor Mechanochromic Torsional Springs
Mechanochromophores based on conformational changes of donor–acceptor–donor (DAD)
springs allow sensing of forces acting on polymer chains by monotonic changes of …
springs allow sensing of forces acting on polymer chains by monotonic changes of …
Force-induced shuttling of rotaxanes controls fluorescence resonance energy transfer in polymer hydrogels
T Muramatsu, S Shimizu, JM Clough… - … Applied Materials & …, 2023 - ACS Publications
The molecular shuttling function of rotaxanes can be exploited to design
mechanoresponsive reporter molecules. Here, we report a new approach to such rotaxane …
mechanoresponsive reporter molecules. Here, we report a new approach to such rotaxane …