Luminescent Complexes of Platinum, Iridium, and Coinage Metals Containing N-Heterocyclic Carbene Ligands: Design, Structural Diversity, and Photophysical …

H Amouri - Chemical Reviews, 2022 - ACS Publications
The employment of N-heterocyclic carbenes (NHCs) to design luminescent metal
compounds has been the focus of recent intense investigations because of the strong σ …

Strategies and mechanisms of metal–ligand cooperativity in first-row transition metal complex catalysts

MR Elsby, RT Baker - Chemical Society Reviews, 2020 - pubs.rsc.org
The use of metal–ligand cooperation (MLC) by transition metal bifunctional catalysts has
emerged at the forefront of homogeneous catalysis science. Specially designed ligands can …

Cyclic (alkyl)-and (aryl)-(amino) carbene coinage metal complexes and their applications

R Jazzar, M Soleilhavoup, G Bertrand - Chemical Reviews, 2020 - ACS Publications
Cyclic (alkyl)-and (aryl)-(amino) carbenes (CAACs and CAArCs) are stronger σ-donors and
π-acceptors than imidazol-2-ylidenes and imidazolidin-2-ylidenes, the well-known N …

Metal N-heterocyclic carbene complexes as potential metallodrugs in antitumor therapy

YF Zhang, YK Yin, H Zhang, YF Han - Coordination Chemistry Reviews, 2024 - Elsevier
Metal complexes, which exhibit alterable oxidation states, coordination numbers, and
capacity to coordinate with different ligands, have provided a versatile platform for designing …

Metals in cancer research: Beyond platinum metallodrugs

A Casini, A Pöthig - ACS Central Science, 2024 - ACS Publications
The discovery of the medicinal properties of platinum complexes has fueled the design and
synthesis of new anticancer metallodrugs endowed with unique modes of action (MoA) …

Photothermal nanofiller-based polydimethylsiloxane anticorrosion coating with multiple cyclic self-healing and long-term self-healing performance

T Wang, W Wang, H Feng, T Sun, C Ma, L Cao… - Chemical Engineering …, 2022 - Elsevier
Self-healing coating is a new strategy for improving the service life of the anticorrosion
coating, however, remaining a challenge to achieve stable, multiple cyclic, and long-term …

TADF: Enabling luminescent copper (I) coordination compounds for light-emitting electrochemical cells

CE Housecroft, EC Constable - Journal of Materials Chemistry C, 2022 - pubs.rsc.org
The last decade has seen a surge of interest in the emissive behaviour of copper (I)
coordination compounds, both neutral compounds that may have applications in organic …

Magnetically recoverable catalysts: Catalysis in synthesis of polyhydroquinolines

M Kazemi, M Mohammadi - Applied Organometallic Chemistry, 2020 - Wiley Online Library
Molecules that contain polyhydroquinoline structural scaffolds are N‐containing
heterocycles which are of great interest to organic chemists and biologists …

Molecular Design Principles to Elongate the Metal-to-Ligand Charge Transfer Excited-State Lifetimes of Square-Planar Nickel (II) Complexes

T Ogawa, N Sinha, B Pfund, A Prescimone… - Journal of the …, 2022 - ACS Publications
Square-planar NiII complexes and their electronically excited states play key roles in cross-
coupling catalysis and could offer new opportunities to complement well-known …

Cobalt–N-heterocyclic carbene complexes in catalysis

SS Bera, M Szostak - ACS catalysis, 2022 - ACS Publications
Cobalt–N-heterocyclic carbene (NHC) complexes have emerged as an attractive class of 3d
transition metal catalysts for a broad range of chemical processes, including cross-coupling …