Electronic defects in metal oxide photocatalysts

E Pastor, M Sachs, S Selim, JR Durrant… - Nature Reviews …, 2022 - nature.com
A deep understanding of defects is essential for the optimization of materials for solar energy
conversion. This is particularly true for metal oxide photo (electro) catalysts, which typically …

The kinetics of metal oxide photoanodes from charge generation to catalysis

S Corby, RR Rao, L Steier, JR Durrant - Nature Reviews Materials, 2021 - nature.com
Generating charge carriers with lifetimes long enough to drive catalysis is a critical aspect for
photoelectrochemical and photocatalytic systems, and a key determinant of their efficiency …

Operando spectroscopies unveil interfacial FeOOH induced highly reactive β-Ni (Fe) OOH for efficient oxygen evolution

Y Li, Y Wu, M Yuan, H Hao, Z Lv, L Xu, B Wei - Applied Catalysis B …, 2022 - Elsevier
Interfacial engineering is an effective strategy for the design of active oxygen evolution
electrode. Yet the intrinsic mechanism of heterogeneous interfaces remains largely unclear …

Particulate photocatalysts for light-driven water splitting: mechanisms, challenges, and design strategies

Q Wang, K Domen - Chemical Reviews, 2019 - ACS Publications
Solar-driven water splitting provides a leading approach to store the abundant yet
intermittent solar energy and produce hydrogen as a clean and sustainable energy carrier. A …

Current understanding and challenges of solar-driven hydrogen generation using polymeric photocatalysts

Y Wang, A Vogel, M Sachs, RS Sprick, L Wilbraham… - Nature Energy, 2019 - nature.com
The use of hydrogen as a fuel, when generated from water using semiconductor
photocatalysts and driven by sunlight, is a sustainable alternative to fossil fuels. Polymeric …

Spectroelectrochemical analysis of the water oxidation mechanism on doped nickel oxides

RR Rao, S Corby, A Bucci… - Journal of the …, 2022 - ACS Publications
Metal oxides and oxyhydroxides exhibit state-of-the-art activity for the oxygen evolution
reaction (OER); however, their reaction mechanism, particularly the relationship between …

Identification of single-atom active sites in carbon-based cobalt catalysts during electrocatalytic hydrogen evolution

L Cao, Q Luo, W Liu, Y Lin, X Liu, Y Cao, W Zhang… - Nature Catalysis, 2019 - nature.com
Monitoring atomic and electronic structure changes on active sites under realistic working
conditions is crucial for the rational design of efficient electrocatalysts. Identification of the …

Advanced catalysts for photoelectrochemical water splitting

MA Marwat, M Humayun, MW Afridi… - ACS Applied Energy …, 2021 - ACS Publications
Photoelectrochemical (PEC) water splitting offers a sparkling and sustainable strategy for
hydrogen generation, and significant research for enhancing the conversion efficiency of …

The bulk heterojunction in organic photovoltaic, photodetector, and photocatalytic applications

A Wadsworth, Z Hamid, J Kosco, N Gasparini… - Advanced …, 2020 - Wiley Online Library
Organic semiconductors require an energetic offset in order to photogenerate free charge
carriers efficiently, owing to their inability to effectively screen charges. This is vitally …

Versatile tools for understanding electrosynthetic mechanisms

ECR McKenzie, S Hosseini, AGC Petro… - Chemical …, 2021 - ACS Publications
Electrosynthesis is a popular, green alternative to traditional organic methods.
Understanding the mechanisms is not trivial yet is necessary to optimize reaction processes …