We present the bulk depolymerization of poly (methyl methacrylate)(PMMA) at significantly
lower temperatures than previously reported methods through the incorporation of …

In this perspective, we explore the historical evolution, photochemical processes, and
distinct utility of photoiniferter polymerization. We aim to provide a practical guide …

In this study, we present an efficient approach for the depolymerization of poly (methyl
methacrylate)(PMMA) copolymers synthesized via conventional radical polymerization. By …

We report the controlled synthesis of ultra-high molecular weight (UHMW) polymers (M n≥
106 g/mol) via continuous flow in a tubular reactor. At high monomer conversion, UHMW …

In controlled radical polymerization, oxygen is typically regarded as an undesirable
component resulting in terminated polymer chains, deactivated catalysts, and subsequent …

We report on a fundamental feature of photoiniferter polymerizations mediated with
trithiocarbonates and xanthates. The polymerizations were found to be highly dependent on …

Compared with conventional thermally initiated radical polymerization, photocontrolled
radical polymerization offers mild, environmentally friendly reaction conditions, fast …

Xanthate-supported photo-iniferter (XPI)-reversible addition–fragmentation chain-transfer
(RAFT) polymerization is introduced as a fast and versatile photo-polymerization strategy …

Photoiniferter polymerization is a straightforward method to produce well-defined ultrahigh
molecular weight (UHMW,> 1 MDa) acrylate polymers, which potentially provides access to …

Reversible deactivation radical polymerization of hydrophilic monomers in water is often
poorly controlled due to several side reactions. It results in polymers with broad molecular …