Organoselenium chemistry: role of intramolecular interactions
In 1836 the first organoselenium compound, diethyl selenide, was prepared by Löwig, 1 and
it was isolated in the pure form in 1869. 2 Early selenium chemistry involved the synthesis of …
it was isolated in the pure form in 1869. 2 Early selenium chemistry involved the synthesis of …
Selenium reagents as catalysts
Organoselenium chemistry has become an important tool in synthetic and medicinal
chemistry. Organoselenium reagents are more commonly known as electrophiles, but there …
chemistry. Organoselenium reagents are more commonly known as electrophiles, but there …
Main group redox catalysis of organopnictogens: vertical periodic trends and emerging opportunities in group 15
JM Lipshultz, G Li, AT Radosevich - Journal of the American …, 2021 - ACS Publications
A growing number of organopnictogen redox catalytic methods have emerged—especially
within the past 10 years—that leverage the plentiful reversible two-electron redox chemistry …
within the past 10 years—that leverage the plentiful reversible two-electron redox chemistry …
Selective difunctionalization of unactivated aliphatic alkenes enabled by a metal–metallaaromatic catalytic system
FH Cui, Y Hua, YM Lin, J Fei, LH Gao… - Journal of the …, 2022 - ACS Publications
The design of organometallic catalysts is crucial in the development of catalytic reactions.
Herein, we describe a heterometallic [Os-Cu] complex with the characteristics of bimetallics …
Herein, we describe a heterometallic [Os-Cu] complex with the characteristics of bimetallics …
[BOOK][B] Organic electrochemistry
O Hammerich, B Speiser - 2016 - api.taylorfrancis.com
Organic electrochemistry is concerned with the reduction and oxidation of organic molecules
at electrodes. Although it is now more than 200 years ago that the so-called Volta pile was …
at electrodes. Although it is now more than 200 years ago that the so-called Volta pile was …
Electrophilic Selenium-Catalyzed Desymmetrizing Cyclization to Access P-Stereogenic Heterocycles
ZC Qi, Y Li, J Wang, L Ma, GW Wang, SD Yang - ACS Catalysis, 2023 - ACS Publications
The construction of phosphorus stereocenters under metal-free conditions remains a
formidable challenge. Herein, we report a mechanistically distinct chiral electrophilic …
formidable challenge. Herein, we report a mechanistically distinct chiral electrophilic …
Organoselenium compounds: Chemistry and applications in organic synthesis
JM Sonego, SI De Diego, SH Szajnman… - … A European Journal, 2023 - Wiley Online Library
Selenium, originally described as a toxin, turns out to be a crucial trace element for life that
appears as selenocysteine and its dimer, selenocystine. From the point of view of drug …
appears as selenocysteine and its dimer, selenocystine. From the point of view of drug …
Electrochemical aminoselenation and oxyselenation of styrenes with hydrogen evolution
L Sun, Y Yuan, M Yao, H Wang, D Wang, M Gao… - Organic …, 2019 - ACS Publications
The use of additive-free conditions is an ideal approach to prepare organoselenium
reagents from readily available unsaturated substrates. Thus, we report the electro-induced …
reagents from readily available unsaturated substrates. Thus, we report the electro-induced …
Organoselenium chemistry-based polymer synthesis
Due to their unique properties, selenium-containing polymers have become one of the
research focuses of polymer materials in recent years. First, selenium can transform among …
research focuses of polymer materials in recent years. First, selenium can transform among …
[BOOK][B] Organoselenium chemistry
T Wirth - 2018 - orca.cardiff.ac.uk
Organoselenium chemistry has been established as a valuable research area in synthetic
and medicinal chemistry. After the discovery of the selenoxide elimination reaction in the …
and medicinal chemistry. After the discovery of the selenoxide elimination reaction in the …