A review of state of the art in phosphine ligated gold clusters and application in catalysis
Atomically precise gold clusters are highly desirable due to their well‐defined structure
which allows the study of structure–property relationships. In addition, they have potential in …
which allows the study of structure–property relationships. In addition, they have potential in …
Toward Solution Syntheses of the Tetrahedral Au20 Pyramid and Atomically Precise Gold Nanoclusters with Uncoordinated Sites
Conspectus A long-standing objective of cluster science is to discover highly stable clusters
and to use them as models for catalysts and building blocks for cluster-assembled materials …
and to use them as models for catalysts and building blocks for cluster-assembled materials …
Understanding ligand effects in gold clusters using mass spectrometry
This review summarizes recent research on the influence of phosphine ligands on the size,
stability, and reactivity of gold clusters synthesized in solution. Sub-nanometer clusters …
stability, and reactivity of gold clusters synthesized in solution. Sub-nanometer clusters …
Reaction Monitoring and Structural Characterisation of Coordination Driven Self-Assembled Systems by Ion Mobility-Mass Spectrometry
Nature creates exquisite molecular assemblies, required for the molecular-level functions of
life, via self-assembly. Understanding and harnessing these complex processes presents an …
life, via self-assembly. Understanding and harnessing these complex processes presents an …
Ligand induced structural isomerism in phosphine coordinated gold clusters revealed by ion mobility mass spectrometry
Structural isomerism in ligated gold clusters is revealed using electrospray ionization ion
mobility spectrometry mass spectrometry. Phosphine ligated Au8 clusters are shown to …
mobility spectrometry mass spectrometry. Phosphine ligated Au8 clusters are shown to …
Size-dependent stability toward dissociation and ligand binding energies of phosphine ligated gold cluster ions
The size-dependent properties of ultra-small gold cluster ions ligated with phosphines are
important to their scalable synthesis and potential applications in catalysis and energy …
important to their scalable synthesis and potential applications in catalysis and energy …
Ion Mobility Spectrometry Characterization of the Intermediate Hydrogen-Containing Gold Cluster Au7(PPh3)7H52+
We employ ion mobility spectrometry and density functional theory to determine the structure
of Au7 (PPh3) 7H52+ (PPh3= triphenylphosphine), which was recently identified by high …
of Au7 (PPh3) 7H52+ (PPh3= triphenylphosphine), which was recently identified by high …
Synthesis, Structural Characterization, and Gas-Phase Unimolecular Reactivity of the Silver Hydride Nanocluster [Ag3((PPh2)2CH2)3(μ3-H)](BF4)2
A Zavras, GN Khairallah, TU Connell… - Inorganic …, 2014 - ACS Publications
A bis (diphenylphosphino) methane-ligated trinuclear silver hydride nanocluster,[Ag3
((Ph2P) 2CH2) 3 (μ3-H)](BF4) 2, featuring three silver (I) ions coordinated to a μ3-hydride …
((Ph2P) 2CH2) 3 (μ3-H)](BF4) 2, featuring three silver (I) ions coordinated to a μ3-hydride …
ESI-MS Identification of the Cationic Phosphine-Ligated Gold Clusters Au1–22: Insight into the Gold–Ligand Ratio and Abundance of Larger Clusters
Triphenylphosphine (PPh3)-ligated gold nanoclusters are valuable for a number of potential
applications due to their relative ease of synthesis and usefulness in forming advanced …
applications due to their relative ease of synthesis and usefulness in forming advanced …
In situ studies on controlling an atomically-accurate formation process of gold nanoclusters
L Yang, H Cheng, Y Jiang, T Huang, J Bao, Z Sun… - Nanoscale, 2015 - pubs.rsc.org
Knowledge of the molecular formation mechanism of metal nanoclusters is essential for
develo** chemistry for accurate control over their synthesis. Herein, the “top-down” …
develo** chemistry for accurate control over their synthesis. Herein, the “top-down” …