Review and new insights into the application of molecular-based equations of state to water and aqueous solutions

LF Vega, F Llovell - Fluid Phase Equilibria, 2016 - Elsevier
Water is a fascinating compound, essential to our life and present in most of the biological
and industrial systems. In spite of its importance, the particular features of water and the …

Evaluation of the PC-SAFT, SAFT and CPA equations of state in predicting derivative properties of selected non-polar and hydrogen-bonding compounds

AJ De Villiers, CE Schwarz, AJ Burger… - Fluid Phase …, 2013 - Elsevier
In order to provide a comprehensive understanding of the potential and limitations of the PC-
SAFT, SAFT and CPA equations-of-state, this study offers insight into their application for the …

SAFT-VR Mie: Application to Phase Equilibria of Alcohols in Mixtures with n-Alkanes and Water

JT Cripwell, SAM Smith, CE Schwarz… - Industrial & …, 2018 - ACS Publications
This work expands the scope of the SAFT-VR Mie framework by considering its application
and that of its polar variant (SAFT-VR Mie-GV) to real phase behavior in alcohol/n-alkane …

Understanding the thermodynamics of hydrogen bonding in alcohol-containing mixtures: cross-association

WA Fouad, L Wang, A Haghmoradi… - The Journal of …, 2016 - ACS Publications
The thermodynamics of hydrogen bonding in 1-alcohol+ water binary mixtures is studied
using molecular dynamic (MD) simulation and the polar and perturbed chain form of the …

[HTML][HTML] New association schemes for tri-ethylene glycol: Cubic-Plus-Association parameterization and uncertainty analysis

D Qvistgaard, F Kruger, X Liang, GM Kontogeorgis… - Fluid Phase …, 2022 - Elsevier
Transportation of natural gas extracted from subterranean reservoirs is subject to several
risks introduced by the presence of water. These risks can be mitigated through subsea …

Understanding the thermodynamics of hydrogen bonding in alcohol-containing mixtures: self association

WA Fouad, L Wang, A Haghmoradi… - The Journal of …, 2015 - ACS Publications
The perturbed chain form of the polar statistical associating fluid theory (Polar PC-SAFT)
was used to model lower 1-alcohol+ n-alkane mixtures. The ability of the equation of state to …

Water+ 1-alkanol systems: Modeling the phase, interface and viscosity properties

F Llovell, O Vilaseca, N Jung, LF Vega - Fluid Phase Equilibria, 2013 - Elsevier
In this work, we present a thermodynamic characterization of the water+ 1-alkanol mixtures,
including the description of phase diagrams, interfacial tension and viscosities, by the soft …

Accounting for cross association in non-self-associating species using a physically consistent SAFT-VR Mie approach

JT Cripwell, FJ Kruger, AJ Burger - Fluid Phase Equilibria, 2019 - Elsevier
This work presents a formalised, physically consistent approach to account for cross
association in the SAFT framework. The focus of the approach was to account for solvation …

Simultaneous modeling of VLE, LLE and VLLE of CO2 and 1, 2, 3 and 4 alkanol containing mixtures using GC-PPC-SAFT EOS

D NguyenHuynh, JP Passarello… - The Journal of …, 2014 - Elsevier
A polar version of the group contribution PC-SAFT equation of state (GC-PPC-SAFT;
Tamouza et al., 2004; NguyenHuynh et al., 2008) combined with a method for …

New association schemes for mono-ethylene glycol: Cubic-Plus-Association parameterization and uncertainty analysis

F Kruger, GM Kontogeorgis, N von Solms - Fluid Phase Equilibria, 2018 - Elsevier
Accurate thermodynamic predictions for systems containing glycols are essential for the
design and commissioning of novel subsea natural gas dehydration units. Previously it has …