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Perspective on Lewis Acid‐Base Interactions in Emerging Batteries
Lewis acid‐base interactions are common in chemical processes presented in diverse
applications, such as synthesis, catalysis, batteries, semiconductors, and solar cells. The …
applications, such as synthesis, catalysis, batteries, semiconductors, and solar cells. The …
9-Borafluorenes: synthesis, properties, and reactivity
This review covers all aspects of 9-borafluorene chemistry, from the first attempted synthesis
in 1960 to the present. This class of molecules consists of a tricyclic system featuring a …
in 1960 to the present. This class of molecules consists of a tricyclic system featuring a …
What distinguishes the strength and the effect of a Lewis acid: analysis of the Gutmann–Beckett method
IUPAC defines Lewis acidity as the thermodynamic tendency for Lewis pair formation. This
strength property was recently specified as global Lewis acidity (gLA), and is gauged for …
strength property was recently specified as global Lewis acidity (gLA), and is gauged for …
An Extensive Set of Accurate Fluoride Ion Affinities for p‐Block Element Lewis Acids and Basic Design Principles for Strong Fluoride Ion Acceptors
The computed fluoride ion affinity (FIA) is a valuable descriptor to assess the Lewis acidity of
a compound. Despite its widespread use, the varying accuracy of applied computational …
a compound. Despite its widespread use, the varying accuracy of applied computational …
Hexafluoroisopropanol as a bioconjugation medium of ultrafast, tryptophan-selective catalysis
The past decade has seen a remarkable growth in the number of bioconjugation techniques
in chemistry, biology, material science, and biomedical fields. A core design element in …
in chemistry, biology, material science, and biomedical fields. A core design element in …
Halogenated triarylboranes: synthesis, properties and applications in catalysis
Halogenated triarylboranes (BAr3) have been known for decades, however it has only been
since the surge of interest in main group catalysis that their application as strong Lewis acid …
since the surge of interest in main group catalysis that their application as strong Lewis acid …
Unique phosphorus-based avenues for the tuning of functional materials
Conspectus Recent ground-breaking advances in synthetic chemistry have transformed
main-group molecules from simple laboratory curiosities into powerful materials for a range …
main-group molecules from simple laboratory curiosities into powerful materials for a range …
Dithienothiophenes at work: Access to mechanosensitive fluorescent probes, chalcogen-bonding catalysis, and beyond
In this review, the multifunctionality of dithieno [3, 2-b: 2′, 3′-d] thiophenes (DTTs) is
covered comprehensively. This is of interest because all involved research is very recent …
covered comprehensively. This is of interest because all involved research is very recent …
An easy-to-perform evaluation of steric properties of Lewis acids
Steric and electronic effects play a very important role in chemistry, as these effects influence
the shape and reactivity of molecules. Herein, an easy-to-perform approach to assess and …
the shape and reactivity of molecules. Herein, an easy-to-perform approach to assess and …
Predicting Lewis Acidity: Machine Learning the Fluoride Ion Affinity of p‐Block‐Atom‐Based Molecules
Abstract “How strong is this Lewis acid?” is a question researchers often approach by
calculating its fluoride ion affinity (FIA) with quantum chemistry. Here, we present FIA49k, an …
calculating its fluoride ion affinity (FIA) with quantum chemistry. Here, we present FIA49k, an …