Formazanate coordination compounds: synthesis, reactivity, and applications

JB Gilroy, E Otten - Chemical Society Reviews, 2020 - pubs.rsc.org
Formazans (Ar1-NH-NCR3-NN-Ar5), a class of nitrogen-rich and highly colored compounds,
have been known since the late 1800s and studied more closely since the early 1940s …

Photostable small-molecule NIR-II fluorescent scaffolds that cross the blood–brain barrier for noninvasive brain imaging

S Wang, H Shi, L Wang, A Loredo… - Journal of the …, 2022 - ACS Publications
The second near-infrared (NIR-II, 1000–1700 nm) fluorescent probes have significant
advantages over visible or NIR-I (600–900 nm) imaging for both depth of penetration and …

Self-assembled organic nanomedicine enables ultrastable photo-to-heat converting theranostics in the second near-infrared biowindow

H **ang, L Zhao, L Yu, H Chen, C Wei, Y Chen… - Nature …, 2021 - nature.com
Abstract Development of organic theranostic agents that are active in the second near-
infrared (NIR-II, 1000–1700 nm) biowindow is of vital significance for treating deep-seated …

Radical‐type reactivity and catalysis by single‐electron transfer to or from redox‐active ligands

JI van der Vlugt - Chemistry–A European Journal, 2019 - Wiley Online Library
Controlled ligand‐based redox‐activity and chemical non‐innocence are rapidly gaining
importance for selective (catalytic) processes. This Concept aims to provide an overview of …

Near‐infrared photoluminescence and electrochemiluminescence from a remarkably simple boron difluoride formazanate dye

RR Maar, R Zhang, DG Stephens… - Angewandte Chemie …, 2019 - Wiley Online Library
A boron difluoride formazanate dye that exhibits near‐infrared photoluminescence and
electrochemiluminescence was produced via a straightforward two‐step synthesis …

Advancements in boron difluoride formazanate dyes for biological imaging

S Yang, K Lu, H **ao - Current opinion in chemical biology, 2024 - Elsevier
In the past decade, boron difluoride formazanate dyes have gained considerable attention
due to their redox activity, high absorption and emission intensities, chemical stability across …

Boron difluorides with formazanate ligands: redox-switchable fluorescent dyes with large stokes shifts

MC Chang, A Chantzis, D Jacquemin, E Otten - Dalton Transactions, 2016 - pubs.rsc.org
The synthesis of a series of (formazanate) boron difluorides and their 1-electron reduction
products is described. The neutral compounds are fluorescent with large Stokes shifts. DFT …

WORM type memory device based on ionic organotin complex using 1, 5-diphenyl-3-(2-pyridyl) formazan ligand

S Birara, A Betal, P Lama, S Sahu, RK Metre - Journal of Molecular …, 2023 - Elsevier
Synthesis, structure, and write once read many (WORM) type memory behavior of an ionic
organotin complex containing a 2-pyridine substituted formazan ligand is described herein …

A solution-processable benzothiazole-substituted formazanate zinc (ii) complex designed for a robust resistive memory device

S Birara, S Saini, M Majumder, SP Tiwari… - Dalton …, 2024 - pubs.rsc.org
A novel mononuclear bis (formazanate) zinc complex (1) based on a redox-active 1-
(benzothiazol-2-yl)-5-(2-benzoyl-4-chlorophenyl)-3-phenyl formazan ligand has been …

π-Conjugated copolymers composed of boron formazanate and their application for a wavelength converter to near-infrared light

Y Kawano, Y Ito, S Ito, K Tanaka, Y Chujo - Macromolecules, 2021 - ACS Publications
We report conjugated polymers consisting of boron formazanate in the main chains. By
employing typical donor-type comonomers, such as fluorene and bithiophene, copolymers …