Controlling a chemical coupling reaction on a surface: tools and strategies for on-surface synthesis

S Clair, DG de Oteyza - Chemical reviews, 2019 - ACS Publications
On-surface synthesis is appearing as an extremely promising research field aimed at
creating new organic materials. A large number of chemical reactions have been …

Covalent on-surface polymerization

L Grill, S Hecht - Nature Chemistry, 2020 - nature.com
With the rapid development of scanning probe microscopy, it has become possible to study
polymerization processes on suitable surfaces at the atomic level and in real space. In the …

Synthesis of mesoscale ordered two-dimensional π-conjugated polymers with semiconducting properties

G Galeotti, F De Marchi, E Hamzehpoor, O MacLean… - Nature materials, 2020 - nature.com
Two-dimensional materials with high charge carrier mobility and tunable band gaps have
attracted intense research effort for their potential use in nanoelectronics. Two-dimensional …

Rationally synthesized two-dimensional polymers

JW Colson, WR Dichtel - Nature chemistry, 2013 - nature.com
Synthetic polymers exhibit diverse and useful properties and influence most aspects of
modern life. Many polymerization methods provide linear or branched macromolecules …

On-surface synthesis of single-layered two-dimensional covalent organic frameworks via solid–vapor interface reactions

XH Liu, CZ Guan, SY Ding, W Wang… - Journal of the …, 2013 - ACS Publications
Surface covalent organic frameworks (SCOFs), featured by atomic thick sheet with
covalently bonded organic building units, are promised to possess unique properties …

[HTML][HTML] Electronic, structural and chemical effects of charge-transfer at organic/inorganic interfaces

R Otero, ALV de Parga, JM Gallego - Surface Science Reports, 2017 - Elsevier
During the last decade, interest on the growth and self-assembly of organic molecular
species on solid surfaces spread over the scientific community, largely motivated by the …

Controlling on-surface polymerization by hierarchical and substrate-directed growth

L Lafferentz, V Eberhardt, C Dri, C Africh, G Comelli… - Nature …, 2012 - nature.com
A key challenge in the field of nanotechnology, in particular in the design of molecular
machines, novel materials or molecular electronics, is the bottom-up construction of …

Surface-catalyzed C–C covalent coupling strategies toward the synthesis of low-dimensional carbon-based nanostructures

Q Fan, JM Gottfried, J Zhu - Accounts of chemical research, 2015 - ACS Publications
Conspectus Carbon-based nanostructures have attracted tremendous interest because of
their versatile and tunable properties, which depend on the bonding type of the constituting …

Homo-coupling of terminal alkynes on a noble metal surface

YQ Zhang, N Kepčija, M Kleinschrodt, K Diller… - Nature …, 2012 - nature.com
The covalent linking of acetylenes presents an important route for the fabrication of novel
carbon-based scaffolds and two-dimensional materials distinct from graphene. To date few …

Surface-assisted Ullmann coupling

M Lackinger - Chemical Communications, 2017 - pubs.rsc.org
Surface-assisted Ullmann coupling is the workhorse of on-surfaces synthesis. Among the
various couplings that were successfully transferred from solution to solid surfaces, Ullmann …