Magnetocaloric effect: From materials research to refrigeration devices

V Franco, JS Blázquez, JJ Ipus, JY Law… - Progress in Materials …, 2018 - Elsevier
The magnetocaloric effect and its most straightforward application, magnetic refrigeration,
are topics of current interest due to the potential improvement of energy efficiency of cooling …

Lanthanide single-molecule magnets

DN Woodruff, REP Winpenny, RA Layfield - Chemical reviews, 2013 - ACS Publications
In the early 1990s, great excitement followed the discovery that a molecular transition metal
coordination compound could, at liquid-helium temperatures, retain magnetization for long …

Recent advances in dysprosium-based single molecule magnets: Structural overview and synthetic strategies

P Zhang, YN Guo, J Tang - Coordination Chemistry Reviews, 2013 - Elsevier
The last few years have seen a huge renaissance in the study of the magnetism of
lanthanide coordination complexes, especially in the field of single molecule magnets …

Toward heterometallic single-molecule magnets: Synthetic strategy, structures and properties of 3d–4f discrete complexes

K Liu, W Shi, P Cheng - Coordination Chemistry Reviews, 2015 - Elsevier
Abstract 3d–4f heterometallic discrete complexes have enjoyed increasing attraction in
recent decades because of their potential advantages to create new single-molecule …

Molecule-based magnetic coolers

YZ Zheng, GJ Zhou, Z Zheng… - Chemical Society …, 2014 - pubs.rsc.org
There has been a rapid expansion in the use of molecular magnets for both low-and ultra
low-temperature cooling applications in recent years, and here we review the chemical …

A trigonal prismatic mononuclear cobalt (II) complex showing single-molecule magnet behavior

VV Novikov, AA Pavlov, YV Nelyubina… - Journal of the …, 2015 - ACS Publications
Single-molecule magnets (SMMs) with one transition-metal ion often rely on unusual
geometry as a source of magnetically anisotropic ground state. Here we report a cobalt (II) …

Relaxation dynamics of dysprosium (III) single molecule magnets

YN Guo, GF Xu, Y Guo, J Tang - Dalton Transactions, 2011 - pubs.rsc.org
Over the past decade, lanthanide compounds have become of increasing interest in the field
of Single Molecule Magnets (SMMs) due to the large inherent anisotropy of the metal ions …

High-nuclearity 3d–4f clusters as enhanced magnetic coolers and molecular magnets

JB Peng, QC Zhang, XJ Kong, YZ Zheng… - Journal of the …, 2012 - ACS Publications
Four 52-metal-ion 3d–4f cluster complexes featuring a common core of Ln42M10 (Ln=
Gd3+, Dy3+; M= Co2+/3+, Ni2+) were obtained through self-assembly of the metal ions …

Filling the gap between the quantum and classical worlds of nanoscale magnetism: giant molecular aggregates based on paramagnetic 3d metal ions

C Papatriantafyllopoulou, EE Moushi… - Chemical Society …, 2016 - pubs.rsc.org
In this review, aspects of the syntheses, structures and magnetic properties of giant 3d and
3d/4f paramagnetic metal clusters in moderate oxidation states are discussed. The term …

Co–Ln mixed-metal phosphonate grids and cages as molecular magnetic refrigerants

YZ Zheng, M Evangelisti, F Tuna… - Journal of the American …, 2012 - ACS Publications
The synthesis, structures, and magnetic properties of six families of cobalt–lanthanide mixed-
metal phosphonate complexes are reported in this Article. These six families can be divided …