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Magnetocaloric effect: From materials research to refrigeration devices
The magnetocaloric effect and its most straightforward application, magnetic refrigeration,
are topics of current interest due to the potential improvement of energy efficiency of cooling …
are topics of current interest due to the potential improvement of energy efficiency of cooling …
Lanthanide single-molecule magnets
In the early 1990s, great excitement followed the discovery that a molecular transition metal
coordination compound could, at liquid-helium temperatures, retain magnetization for long …
coordination compound could, at liquid-helium temperatures, retain magnetization for long …
Recent advances in dysprosium-based single molecule magnets: Structural overview and synthetic strategies
P Zhang, YN Guo, J Tang - Coordination Chemistry Reviews, 2013 - Elsevier
The last few years have seen a huge renaissance in the study of the magnetism of
lanthanide coordination complexes, especially in the field of single molecule magnets …
lanthanide coordination complexes, especially in the field of single molecule magnets …
Toward heterometallic single-molecule magnets: Synthetic strategy, structures and properties of 3d–4f discrete complexes
K Liu, W Shi, P Cheng - Coordination Chemistry Reviews, 2015 - Elsevier
Abstract 3d–4f heterometallic discrete complexes have enjoyed increasing attraction in
recent decades because of their potential advantages to create new single-molecule …
recent decades because of their potential advantages to create new single-molecule …
Molecule-based magnetic coolers
YZ Zheng, GJ Zhou, Z Zheng… - Chemical Society …, 2014 - pubs.rsc.org
There has been a rapid expansion in the use of molecular magnets for both low-and ultra
low-temperature cooling applications in recent years, and here we review the chemical …
low-temperature cooling applications in recent years, and here we review the chemical …
A trigonal prismatic mononuclear cobalt (II) complex showing single-molecule magnet behavior
Single-molecule magnets (SMMs) with one transition-metal ion often rely on unusual
geometry as a source of magnetically anisotropic ground state. Here we report a cobalt (II) …
geometry as a source of magnetically anisotropic ground state. Here we report a cobalt (II) …
Relaxation dynamics of dysprosium (III) single molecule magnets
YN Guo, GF Xu, Y Guo, J Tang - Dalton Transactions, 2011 - pubs.rsc.org
Over the past decade, lanthanide compounds have become of increasing interest in the field
of Single Molecule Magnets (SMMs) due to the large inherent anisotropy of the metal ions …
of Single Molecule Magnets (SMMs) due to the large inherent anisotropy of the metal ions …
High-nuclearity 3d–4f clusters as enhanced magnetic coolers and molecular magnets
JB Peng, QC Zhang, XJ Kong, YZ Zheng… - Journal of the …, 2012 - ACS Publications
Four 52-metal-ion 3d–4f cluster complexes featuring a common core of Ln42M10 (Ln=
Gd3+, Dy3+; M= Co2+/3+, Ni2+) were obtained through self-assembly of the metal ions …
Gd3+, Dy3+; M= Co2+/3+, Ni2+) were obtained through self-assembly of the metal ions …
Filling the gap between the quantum and classical worlds of nanoscale magnetism: giant molecular aggregates based on paramagnetic 3d metal ions
In this review, aspects of the syntheses, structures and magnetic properties of giant 3d and
3d/4f paramagnetic metal clusters in moderate oxidation states are discussed. The term …
3d/4f paramagnetic metal clusters in moderate oxidation states are discussed. The term …
Co–Ln mixed-metal phosphonate grids and cages as molecular magnetic refrigerants
YZ Zheng, M Evangelisti, F Tuna… - Journal of the American …, 2012 - ACS Publications
The synthesis, structures, and magnetic properties of six families of cobalt–lanthanide mixed-
metal phosphonate complexes are reported in this Article. These six families can be divided …
metal phosphonate complexes are reported in this Article. These six families can be divided …