Supramolecular helical systems: helical assemblies of small molecules, foldamers, and polymers with chiral amplification and their functions

E Yashima, N Ousaka, D Taura, K Shimomura… - Chemical …, 2016 - ACS Publications
In this review, we describe the recent advances in supramolecular helical assemblies
formed from chiral and achiral small molecules, oligomers (foldamers), and helical and …

Recognition in the domain of molecular chirality: from noncovalent interactions to separation of enantiomers

P Peluso, B Chankvetadze - Chemical Reviews, 2022 - ACS Publications
It is not a coincidence that both chirality and noncovalent interactions are ubiquitous in
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …

Functional π-gelators and their applications

SS Babu, VK Praveen, A Ajayaghosh - Chemical reviews, 2014 - ACS Publications
Supramolecular chemistry originally defined by Lehn as “chemistry beyond molecules”
exploits noncovalent interactions between molecules to form 1D, 2D, and 3D …

Recent progress on circularly polarized luminescent materials for organic optoelectronic devices

J Han, S Guo, H Lu, S Liu, Q Zhao… - Advanced Optical …, 2018 - Wiley Online Library
Due to the characteristics of optical rotation, selective emission of polarized light, and
circular dichroism, circularly polarized luminescent materials have aroused extensive …

Chiral supramolecular polymers

F García, R Gómez, L Sánchez - Chemical Society Reviews, 2023 - pubs.rsc.org
As an active branch within the field of supramolecular polymers, chiral supramolecular
polymers (SPs) are an excellent benchmark to generate helical structures that can clarify the …

Deuterium‐and tritium‐labelled compounds: applications in the life sciences

J Atzrodt, V Derdau, WJ Kerr… - Angewandte chemie …, 2018 - Wiley Online Library
Hydrogen isotopes are unique tools for identifying and understanding biological and
chemical processes. Hydrogen isotope labelling allows for the traceless and direct …

A field guide to foldamers

DJ Hill, MJ Mio, RB Prince, TS Hughes… - Chemical …, 2001 - ACS Publications
The breadth of structure and function displayed by the molecules of biology is remarkable.
Considering that there are only three major biopolymer backbones (proteins, ribonucleic …

Helical polymers: synthesis, structures, and functions

E Yashima, K Maeda, H Iida, Y Furusho… - Chemical …, 2009 - ACS Publications
The helix is the central structural motif in biological macromolecules, such as DNA and
proteins, and is also the ubiquitous object in nature from microscopic to macroscopic points …

Prebiotic systems chemistry: new perspectives for the origins of life

K Ruiz-Mirazo, C Briones, A de la Escosura - Chemical reviews, 2014 - ACS Publications
The origin of life is a fascinating, unresolved problem whose deciphering would have
important scientific, epistemological and social implications. Over time, philosophers and …

Efficient separation of enantiomers using stereoregular chiral polymers

J Shen, Y Okamoto - Chemical reviews, 2016 - ACS Publications
Biosystems, including ourselves, are very sensitive to the chirality of compounds; for
instance, monosodium L-glutamate is tasty, while its D-isomer is tasteless, and in many …