Sunlight-driven water splitting to produce hydrogen fuel has stimulated intensive scientific
interest, as this technology has the potential to revolutionize fossil fuel-based energy …

Conspectus The hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and
oxygen reduction reaction (ORR) are involved in biological and artificial energy conversions …

Porphyrin-based frameworks, as specific kinds of metal–organic frameworks (MOFs) and
covalent organic frameworks (COFs), have been widely used in energy-related conversion …

Corrole chemistry has witnessed an impressive boost in studies in the last 20 years, thanks
to the possibility of preparing corrole derivatives by simple synthetic procedures. The …

Nature uses Fe porphyrin sites for the oxygen reduction reaction (ORR). Synthetic Fe
porphyrins have been extensively studied as ORR catalysts, but activity improvement is …

Synthesizing molecule@ support hybrids is appealing to improve molecular electrocatalysis.
We report herein metal–organic framework (MOF)‐supported Co porphyrins for the oxygen …

As oxygen evolution reaction (OER) being a critical and bottleneck reaction in a wide range
of energy applications, searching for highly-efficient OER electrocatalysts is of great …

Water nucleophilic attack (WNA) on high-valent terminal Mn-oxo species is proposed for O–
O bond formation in natural and artificial water oxidation. Herein, we report an …

Proton transfer is vital for many biological and chemical reactions. Hydrogen‐bonded water‐
containing networks are often found in enzymes to assist proton transfer, but similar strategy …

With the goal for remarkably enhancing the catalytic activity and ultimately maximizing the
atom efficiency, atomically dispersed metal catalysts (ADMCs) have grown rapidly in the …