The halogen-atom transfer (XAT) is one of the most important and applied processes for the
generation of carbon radicals in synthetic chemistry. In this review, we summarize and …

The advent of sulfur (vi)-fluoride exchange (SuFEx) processes as transformations with click-
like reactivity has invigorated research into electrophilic species featuring a sulfur–fluorine …

Sulfur (VI) fluoride exchange (SuFEx) gives rise to a plethora of high-valent sulfur linkages;
however, the availability of (aliphatic) sulfonyl fluoride manifolds lag behind, owing to the …

All fluorochemicals—including elemental fluorine and nucleophilic, electrophilic, and radical
fluorinating reagents—are prepared from hydrogen fluoride (HF). This highly toxic and …

Recently, radical fluorosulfonylation is emerging as an appealing approach for the synthesis
of sulfonyl fluorides, which are highly in demand in various disciplines, particularly in …

Current medicinal chemistry relies heavily on the quality of building blocks, ie reagents used
to introduce chemical diversity into the target molecules. The last decade witnessed an …

Sulfonyl fluorides are useful building blocks in a wide array of fields. Herein, we report a
catalytic decarboxylative fluorosulfonylation approach for converting abundant aliphatic …

Sulfonyl fluorides display unique reactivity in organic synthesis and have wide applications
in drug discovery, chemical biology, and materials science. Against the backdrop of …

The development of efficient approaches to access sulfonyl fluorides is of great significance
because of the widespread applications of these structural motifs in many areas, among …

Since the sulfur (VI) fluoride exchange reaction (SuFEx) was introduced by Sharpless and
co-workers in 2014, this new-generation click chemistry has emerged as an efficient and …