Recent advances in the synthesis of functionalised monofluorinated compounds
S Fustero, DM Sedgwick, R Román… - Chemical …, 2018 - pubs.rsc.org
Over the past few years, we have tackled the synthesis of interesting monofluorinated
organic molecules, such as: dihydronaphthalene derivatives, β-fluoro sulfones and related …
organic molecules, such as: dihydronaphthalene derivatives, β-fluoro sulfones and related …
Anti-Markovnikov alkene oxidation by metal-oxo–mediated enzyme catalysis
Catalytic anti-Markovnikov oxidation of alkene feedstocks could simplify synthetic routes to
many important molecules and solve a long-standing challenge in chemistry. Here we report …
many important molecules and solve a long-standing challenge in chemistry. Here we report …
Palladium-Catalyzed Anti-Markovnikov Oxidation of Aromatic and Aliphatic Alkenes to Terminal Acetals and Aldehydes
Y Ura - Synthesis, 2021 - thieme-connect.com
Catalytic anti-Markovnikov (AM) oxidation of terminal alkenes can provide terminally
oxyfunctionalized organic compounds. This short review mainly summarizes our recent …
oxyfunctionalized organic compounds. This short review mainly summarizes our recent …
Electronic asymmetry of an annelated pyridyl–mesoionic carbene scaffold: application in Pd (II)-Catalyzed wacker-type oxidation of olefins
The two donor modules of an annelated pyridyl–mesoionic carbene ligand (aPmic) have
different σ-and π-bonding characteristics leading to its electronic asymmetry. A Pd (II) …
different σ-and π-bonding characteristics leading to its electronic asymmetry. A Pd (II) …
Palladium-Catalyzed Carbonylation of Amines with Mo(CO)6 as the Carbonyl Source
B Zhang, W Deng, ZY Xu - Organometallics, 2023 - ACS Publications
Catalytic carbonylation of transition metals is widely used as an effective means to
synthesize carbonyl-containing compounds. In this article, we introduce a method for the …
synthesize carbonyl-containing compounds. In this article, we introduce a method for the …
Progress in the synthesis of aldehydes from Pd-catalyzed Wacker-type reactions of terminal olefins
J Muzart - Tetrahedron, 2021 - Elsevier
Wacker-type reactions of terminal alkenes mainly lead to methyl ketones rather than
aldehydes. The selective formation of aldehydes usually requires alkenes containing a …
aldehydes. The selective formation of aldehydes usually requires alkenes containing a …
Iodine (III)-Mediated Fluorination/Semipinacol Rearrangement Cascade of 2-Alkylidenecyclobutanol Derivatives: Access to β-Monofluorinated …
SX Feng, S Yang, FH Tu, PP Lin… - The Journal of …, 2021 - ACS Publications
A hypervalent iodine (III)-mediated ring-contractive fluorination reaction of 2-
alkylidenecyclobutanol derivatives is presented. The protocol allows the facile synthesis of β …
alkylidenecyclobutanol derivatives is presented. The protocol allows the facile synthesis of β …
Distinctive ligand effects of functionalized magnetic microparticles immobilizing palladium acetate as heterogeneous coordination catalysts for selective oxidation of …
Y Long, Z Zhao, L Wu, S Luo, H Wen, W Wu, H Zhang… - Molecular …, 2017 - Elsevier
A series of functionalized magnetic nanoparticles immobilizing palladium acetate with
different ligands, including β-diketimine, Schiff base and (3-aminopropyl) triethoxysilane …
different ligands, including β-diketimine, Schiff base and (3-aminopropyl) triethoxysilane …
Palladium/Copper‐catalyzed Oxidation of Aliphatic Terminal Alkenes to Aldehydes Assisted by p‐Benzoquinone
S Komori, Y Yamaguchi, Y Murakami… - …, 2020 - Wiley Online Library
The development of an anti‐Markovnikov Wacker‐type oxidation for simple aliphatic alkenes
is a significant challenge. Herein, a variety of aldehydes can be selectively obtained from …
is a significant challenge. Herein, a variety of aldehydes can be selectively obtained from …
Palladium-Catalyzed Aerobic Anti-Markovnikov Oxidation of Aliphatic Alkenes to Terminal Acetals
S Komori, Y Yamaguchi, Y Kataoka… - The Journal of Organic …, 2019 - ACS Publications
Terminal acetals were selectively synthesized from various unbiased aliphatic terminal
alkenes and 1, 2-, 1, 3-, or 1, 4-diols using a PdCl2 (MeCN) 2/CuCl catalyst system in the …
alkenes and 1, 2-, 1, 3-, or 1, 4-diols using a PdCl2 (MeCN) 2/CuCl catalyst system in the …