Solar‐to‐H2O2 Catalyzed by Covalent Organic Frameworks

Z Yong, T Ma - Angewandte Chemie, 2023 - Wiley Online Library
Benefiting from the excellent structural tunability, robust framework, ultrahigh porosity, and
rich active sites, covalent organic frameworks (COFs) are widely recognized as promising …

Carbon nitride based materials: more than just a support for single-atom catalysis

GFSR Rocha, MAR da Silva, A Rogolino… - Chemical Society …, 2023 - pubs.rsc.org
Recently, the missing link between homogeneous and heterogeneous catalysis has been
found and it was named single-atom catalysis (SAC). However, the SAC field still faces …

Enhancing photocatalytic H2O2 production with Au co-catalysts through electronic structure modification

X Zhang, D Gao, B Zhu, B Cheng, J Yu, H Yu - Nature Communications, 2024 - nature.com
Gold-based co-catalysts are a promising class of materials with potential applications in
photocatalytic H2O2 production. However, current approaches with Au co-catalysts show …

Develo** Ni single-atom sites in carbon nitride for efficient photocatalytic H2O2 production

X Zhang, H Su, P Cui, Y Cao, Z Teng, Q Zhang… - Nature …, 2023 - nature.com
Photocatalytic two-electron oxygen reduction to produce high-value hydrogen peroxide
(H2O2) is gaining popularity as a promising avenue of research. However, structural …

H2O2 generation from O2 and H2O on a near-infrared absorbing porphyrin supramolecular photocatalyst

Y Zhang, C Pan, G Bian, J Xu, Y Dong, Y Zhang, Y Lou… - Nature Energy, 2023 - nature.com
Abstract Hydrogen peroxide (H2O2) is an important industrial chemical and also a possible
energy carrier. Photocatalytic synthesis of H2O2 is an attractive alternative to the …

Covalent organic frameworks for direct photosynthesis of hydrogen peroxide from water, air and sunlight

F Liu, P Zhou, Y Hou, H Tan, Y Liang, J Liang… - Nature …, 2023 - nature.com
Solar-driven photosynthesis is a sustainable process for the production of hydrogen
peroxide, the efficiency of which is plagued by side reactions. Metal-free covalent organic …

Sulfone‐Modified Covalent Organic Frameworks Enabling Efficient Photocatalytic Hydrogen Peroxide Generation via One‐Step Two‐Electron O2 Reduction

Y Luo, B Zhang, C Liu, D **a, X Ou… - Angewandte Chemie …, 2023 - Wiley Online Library
Photocatalytic oxygen reduction reaction (ORR) offers a promising hydrogen peroxide
(H2O2) synthetic strategy, especially the one‐step two‐electron (2e−) ORR route holds great …

Shear Stress Triggers Ultrathin-Nanosheet Carbon Nitride Assembly for Photocatalytic H2O2 Production Coupled with Selective Alcohol Oxidation

Q Li, Y Jiao, Y Tang, J Zhou, B Wu… - Journal of the American …, 2023 - ACS Publications
Coupled photocatalysis without cocatalysts can maximize the utilization of photons and
atoms, which puts forward higher demands on photocatalysts. Polymeric carbon nitride (CN) …

Integrating Bifunctionality and Chemical Stability in Covalent Organic Frameworks via One-Pot Multicomponent Reactions for Solar-Driven H2O2 Production

P Das, G Chakraborty, J Roeser, S Vogl… - Journal of the …, 2023 - ACS Publications
Multicomponent reactions (MCRs) can be used to introduce different functionalities into
highly stable covalent organic frameworks (COFs). In this work, the irreversible three …

Oxidation‐Reduction Molecular Junction Covalent Organic Frameworks for Full Reaction Photosynthesis of H2O2

JN Chang, Q Li, JW Shi, M Zhang, L Zhang… - Angewandte …, 2023 - Wiley Online Library
The full reaction photosynthesis of H2O2 that can combine water‐oxidation and oxygen‐
reduction without sacrificial agents is highly demanded to maximize the light‐utilization and …