π-Conjugated zwitterions as paradigm of donor–acceptor building blocks in organic-based materials

L Beverina, GA Pagani - Accounts of Chemical Research, 2014 - ACS Publications
The very peculiar characteristics of zwitterions, as well as a clearand unambiguous
definition, have been overlooked in past literature. However, these compounds are …

Ultra-high-response, multiply twisted electro-optic chromophores: influence of π-system elongation and interplanar torsion on hyperpolarizability

Y Shi, D Frattarelli, N Watanabe… - Journal of the …, 2015 - ACS Publications
The systematic synthesis, structural, optical spectroscopic, and second-order nonlinear
optical (NLO) characterization of a series of donor–acceptor poly-arylene chromophores …

Organoimido-polyoxometalate nonlinear optical chromophores: A structural, spectroscopic, and computational study

A Al-Yasari, N Van Steerteghem, H Kearns… - Inorganic …, 2017 - ACS Publications
Ten organoimido polyoxometalate (POM)-based chromophores have been synthesized and
studied by hyper-Rayleigh scattering (HRS), Stark and Resonance Raman spectroscopies …

Donor–acceptor organo-imido polyoxometalates: high transparency, high activity redox-active NLO chromophores

A Al-Yasari, N Van Steerteghem, H El Moll… - Dalton …, 2016 - pubs.rsc.org
We show that polyoxometalates (POMs) are an excellent redox-active acceptor on which to
base high performance 2nd order non-linear optical (NLO) chromophores. This is …

Synthesis and Optical and Nonlinear Optical Properties of Linear and Two-Dimensional Charge Transfer Chromophores Based on Polyoxometalates

BR Hood, Y de Coene, CF Jones… - Inorganic …, 2024 - ACS Publications
We present the first study of arylimido-polyoxometalate nonlinear optical (NLO)
chromophores with two-dimensional (2D) structures, and a comparison with one …

N‐Methyl‐4‐pyridinium Tetrazolate Zwitterion‐Based Photochromic Materials

XY Chen, NN Zhang, LZ Cai, PX Li… - … A European Journal, 2017 - Wiley Online Library
Abstract N, N′‐Disubstituted bipyridinium (viologen) and N‐monosubstituted bipyridinium
compounds are well known for their electron‐transfer (ET) photochromic behavior. Their …

Electrochemically‐Switched 2nd Order Non‐Linear Optical Response in an Arylimido‐Polyoxometalate with High Contrast and Cyclability

BR Hood, Y de Coene… - Angewandte Chemie …, 2023 - Wiley Online Library
Electrochemically switched 2nd order non‐linear optical responses have been
demonstrated for the first time in polyoxometalates (POMs), with an arylimido‐derivative …

Photochromic lanthanide (III) materials with ion sensing based on pyridinium tetrazolate zwitterion

LZ Cai, XY Chen, MS Wang, GC Guo - ACS omega, 2019 - ACS Publications
Lanthanide (III) ion (Ln (III)) sensing has become a major research area owing to its
intriguing prospect in clinic, biology, and environmental studies. However, the existing …

NLOphoric rigid pyrazino-phenanthroline donor-π-acceptor compounds: Investigation of structural and solvent effects on non-linear optical properties using …

S Kothavale, S Katariya, N Sekar - Optical Materials, 2018 - Elsevier
Rigid pyrazino-phenanthroline based donor-π-acceptor-π-auxiliary acceptor type
compounds have been studied for their linear and non-linear optical properties. The non …

[PDF][PDF] Crystal structure or chemical composition of salt–sugar-based metal–organic frameworks: what are the nonlinear optical properties due to?

D Marabello, P Antoniotti, P Benzi… - … Section B: Structural …, 2021 - journals.iucr.org
In the last few decades optical imaging techniques based on nonlinear optical properties
have been of interest for biosensing applications. This work focuses on two isostructural and …