Strategies towards single-chain magnets

HL Sun, ZM Wang, S Gao - Coordination Chemistry Reviews, 2010 - Elsevier
Single-chain magnets (SCM) are a novel class of molecular magnetic materials exhibiting
slow magnetic relaxation, which arises from large uniaxial type magnetic anisotropy, strong …

Single-chain magnets: theoretical approach and experimental systems

C Coulon, H Miyasaka, R Clérac - Single-molecule magnets and related …, 2006 - Springer
Recently, a new class of nano-magnets has been discovered and called single-chain
magnets (SCMs) by analogy to the single-molecule magnets (SMMs). These materials are …

Recent progress on cyano-bridged transition-metal-based single-molecule magnets and single-chain magnets

JH Wang, ZY Li, M Yamashita, XH Bu - Coordination Chemistry Reviews, 2021 - Elsevier
Novel functional molecular-based magnetic materials, especially some members of the
Prussian blue family, have gained significant attention over the past few decades as they …

Slow dynamics of the magnetization in one-dimensional coordination polymers: single-chain magnets

H Miyasaka, M Julve, M Yamashita… - Inorganic chemistry, 2009 - ACS Publications
Slow relaxation of the magnetization (ie,“magnet-like” behavior) in materials composed of
magnetically isolated chains was observed for the first time in 2001. This type of behavior …

Design of single chain magnets through cyanide-bearing six-coordinate complexes

R Lescouëzec, LM Toma, J Vaissermann… - Coordination chemistry …, 2005 - Elsevier
The design and preparation of stable cyanide-bearing six-coordinate complexes of formula
[MIII (L)(CN) x](x+ l− m)−(M= trivalent transition metal ion and L= polydentate blocking …

Single-Chain Magnet (NEt4)[Mn2(5-MeOsalen)2Fe(CN)6] Made of MnIII−FeIII−MnIII Trinuclear Single-Molecule Magnet with an ST = 9/2 Spin Ground …

M Ferbinteanu, H Miyasaka… - Journal of the …, 2005 - ACS Publications
The cyano-bridged trinuclear compound,(NEt4)[Mn2 (salmen) 2 (MeOH) 2Fe (CN)
6](1)(salmen2-= rac-N, N '-(1-methylethylene) bis (salicylideneiminate)), reported previously …

A toolbox of building blocks, linkers and crystallisation methods used to generate single-chain magnets

S Dhers, HLC Feltham, S Brooker - Coordination Chemistry Reviews, 2015 - Elsevier
Single-molecule magnets (SMMs) and single-chain magnets (SCMs) are potential
candidates for more dense data storage and quantum computing as well as providing …

A promising new route towards single-molecule magnets based on the oxalate ligand

GF Xu, QL Wang, P Gamez, Y Ma, R Clérac… - Chemical …, 2010 - pubs.rsc.org
A unique purely lanthanide-based single-molecule magnet (SMM) with an oxalate bridge
has been designed through a rational synthetic approach. This strategy opens up new …

Slow relaxation processes and single-ion magnetic behaviors in dysprosium-containing complexes

Y Wang, XL Li, TW Wang, Y Song, XZ You - Inorganic chemistry, 2010 - ACS Publications
A series of one-dimensional complexes [Ln (L1) 3 (HOCH2CH2OH)] n (L1= 2-furoate anion;
Ln= Nd (1), Sm (2), Gd (3), Tb (4), Dy (5), Er (6)) have been synthesized. The complexes …

Trigonal antiprismatic Co (II) single molecule magnets with large uniaxial anisotropies: importance of Raman and tunneling mechanisms

YZ Zhang, S Gómez-Coca, AJ Brown, MR Saber… - Chemical …, 2016 - pubs.rsc.org
The air-stable mononuclear Co (II) compounds [CoII (Tpm) 2][ClO4] 2 (1, Tpm= tris (pyrazol-
1-yl) methane),[CoII (Tpm) 2][BPh4] 2· 2MeCN (2) with trigonal antiprismatic geometry …