Building better full manganese-based cathode materials for next-generation lithium-ion batteries

J Song, H Wang, Y Zuo, K Zhang, T Yang… - Electrochemical Energy …, 2023 - Springer
Lithium-manganese-oxides have been exploited as promising cathode materials for many
years due to their environmental friendliness, resource abundance and low biotoxicity …

A Mechanistic Insight into the Oxygen Redox of Li‐Rich Layered Cathodes and their Related Electronic/Atomic Behaviors Upon Cycling

S Kang, D Choi, H Lee, B Choi, YM Kang - Advanced Materials, 2023 - Wiley Online Library
Li‐rich cathodes are extensively investigated as their energy density is superior to Li
stoichiometric cathode materials. In addition to the transition metal redox, this intriguing …

A Li-rich layered oxide cathode with negligible voltage decay

D Luo, H Zhu, Y **a, Z Yin, Y Qin, T Li, Q Zhang, L Gu… - Nature Energy, 2023 - nature.com
With high capacity at low cost, Li-and Mn-rich (LMR) layered oxides are a promising class of
cathodes for next-generation Li-ion batteries. However, substantial voltage decay during …

Achieving a high-performance sodium-ion pouch cell by regulating intergrowth structures in a layered oxide cathode with anionic redox

X Wang, Q Zhang, C Zhao, H Li, B Zhang, G Zeng… - Nature Energy, 2024 - nature.com
In P2-type layered transition metal (TM) oxides, which are typical cathode materials for Na-
ion batteries, the presence of Li within the TM layer could lead to the formation of specific Na …

Decoupling the roles of Ni and Co in anionic redox activity of Li-rich NMC cathodes

B Li, Z Zhuo, L Zhang, A Iadecola, X Gao, J Guo… - Nature Materials, 2023 - nature.com
Abstract Li [Li x Ni y Mn z Co1− x− y− z] O2 (lithium-rich NMCs) are benchmark cathode
materials receiving considerable attention due to the abnormally high capacities resulting …

Oxide cathodes: functions, instabilities, self healing, and degradation mitigations

Y Dong, J Li - Chemical Reviews, 2022 - ACS Publications
Recent progress in high-energy-density oxide cathodes for lithium-ion batteries has pushed
the limits of lithium usage and accessible redox couples. It often invokes hybrid anion-and …

Understanding Lattice Oxygen Redox Behavior in Lithium‐Rich Manganese‐Based Layered Oxides for Lithium‐Ion and Lithium‐Metal Batteries from Reaction …

C Shen, L Hu, Q Duan, X Liu, S Huang… - Advanced Energy …, 2023 - Wiley Online Library
Lithium‐rich manganese‐based layered oxides (LMLOs) are considered to be one type of
the most promising materials for next‐generation cathodes of lithium batteries due to their …

Self-constructing a lattice-oxygen-stabilized interface in Li-rich cathodes to enable high-energy all-solid-state batteries

X Xu, S Chu, S Xu, S Guo, H Zhou - Energy & Environmental Science, 2024 - pubs.rsc.org
Employing lithium-rich oxides as cathode materials offers an ideal option for achieving high-
energy all-solid-state lithium batteries (ASSLBs), while lithium-rich cathode materials are …

Sulfur‐assisted surface modification of lithium‐rich manganese‐based oxide toward high anionic redox reversibility

Z Xu, X Guo, W Song, J Wang, T Qin… - Advanced …, 2024 - Wiley Online Library
Energy storage via anionic redox provides extra capacity for lithium‐rich manganese‐based
oxide cathodes at high voltage but causes gradual structural collapse and irreversible …

Highly reversible transition metal migration in superstructure-free Li-rich oxide boosting voltage stability and redox symmetry

T Cui, J Xu, X Wang, L Liu, Y **ang, H Zhu, X Li… - Nature …, 2024 - nature.com
The further practical applications of Li-rich layered oxides are impeded by voltage decay
and redox asymmetry, which are closely related to the structural degradation involving …