Chemical evolution of CO2 ices under processing by ionizing radiation: Characterization of nonobserved species and chemical equilibrium phase with the …

S Pilling, GA Carvalho, WRM Rocha - The Astrophysical Journal, 2022 - iopscience.iop.org
Astrophysical ices are being exposed to ionizing radiation in space environments, which
trigger new reactions and desorption processes. In the lab, such processing by radiation has …

Map** the evolution of pure CO2 ices irradiated by ions, UV, and electrons using the upgraded PROCODA code (employing an effective rate constant ordering by …

S Pilling, WRM Rocha, GA Carvalho… - Advances in Space …, 2023 - Elsevier
Chemical reactions and desorption processes are being triggered by incoming ionizing
radiation over astrophysical ices in cold space environments. The quantification of these …

Characterization of acetonitrile ice irradiated by X-rays employing the procoda code – I. Effective rate constants and abundances at chemical equilibrium

GA Carvalho, S Pilling… - Monthly Notices of the …, 2022 - academic.oup.com
In this work, the chemical evolution of pure acetonitrile ice at 13 K irradiated with broad-band
soft X-rays (from 6 eV to 2 keV) is determined by using a computational methodology …

Synthesis of interstellar propen-2-ol (CH 3 C (OH) CH 2)–the simplest enol tautomer of a ketone

J Wang, AA Nikolayev, C Zhang, JH Marks… - Physical Chemistry …, 2023 - pubs.rsc.org
Enols–tautomers of ketones or aldehydes–are anticipated to be ubiquitous in the interstellar
medium and play a key role in the formation of complex organic molecules in deep space …

Chemical evolution of electron-bombarded crystalline water ices at different temperatures using the procoda code

S Pilling, CH da Silveira… - Monthly Notices of the …, 2023 - academic.oup.com
Water ices are a common component of cold space environments, including molecular and
protostellar clouds, and the frozen surfaces of moons, planets, and comets. When exposed …

Characterization of acetonitrile ice irradiated by X-rays employing the procoda code – II. Desorption processes

GA Carvalho, S Pilling… - Monthly Notices of the …, 2024 - academic.oup.com
In this work, we focus on the study of radiation-induced desorption processes that occurred
in acetonitrile ice irradiated by broad-band X-rays (6 eV to 2 keV) monitored by Fourier …

Photolysis of CH3CN Ices by Soft X-rays: Implications for the Chemistry of Astrophysical Ices at the Surroundings of X-ray Sources

GA Carvalho, S Pilling - The Journal of Physical Chemistry A, 2020 - ACS Publications
In this work, broad-band soft X-ray (6–2000 eV) was employed to irradiate frozen acetonitrile
CH3CN, at the temperature 13 K, with different photon fluences up to 1.5× 1018 photons cm …

Chemical changes induced during heating of acetonitrile-rich ice pre-irradiated by X-rays and its implication in astrochemistry

GA Carvalho, S Pilling - Spectrochimica Acta Part A: Molecular and …, 2022 - Elsevier
In this work, we investigate the effects induced by the heating of acetonitrile-rich ice from 13
K to 350 K. Before the heating, the sample was irradiated at 13 K by broadband X-rays (6 eV …

FOTÓLISE DE GELO DE ÁGUA POR RAIOS-X MOLES EA PRODUÇÃO DE H2O2 DURANTE AS FASES DE IRRADIAÇÃO E AQUECIMENTO

SPG de Oliveira, RC da Silva - Revista Univap, 2023 - revista.univap.br
Gelos astrofísicos ricos em H 2 O (água) estão sempre expostos a radiações ionizantes no
espaço, assim como a eventuais mudanças de temperatura. Seus estudos em laboratório …

Understanding Decomposition Mechanism of Acetone under Electric Pulsed Discharge: Generation of C3O+ and C3H4O+ ions

P Sharma, S Das, C Majumder - ChemistrySelect, 2024 - Wiley Online Library
Gas‐phase investigations on acetone, under the influence of electric pulsed discharge has
provided distinct insight related to its decomposition. Time‐of‐flight mass spectrometry has …