The Vinylogous Aldol and Related Addition Reactions: Ten Years of Progress | Chemical
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The nucleophilic addition of carbon nucleophiles to amides has traditionally been a difficult
task, both due to reactivity and selectivity problems. When successful, these processes …

A new asymmetric entry of the 1, 2-aza-Friedel− Crafts reaction catalyzed by a chiral
phosphoric acid is described. The present reaction has provided an atom-economical route …

Over the past decade, asymmetric aminocatalysis has become a reliable synthetic platform
for generating stereogenic centres at the α and β positions of unmodified carbonyl …

α‐Verzweigung ergibt γ‐Alkylierung: Die enantioselektive direkte γ‐Alkylierung von α‐
substituierten α, β‐ungesättigten Aldehyden gelang unter Dienamin‐Katalyse. Ein …

Nucleophilic addition to carbon-nitrogen double bonds is one of the most practiced methods
for the synthesis of nitrogen derivatives. 1-4 In terms of reactivity, a logical comparison with …

Iron (III) chloride catalyzes the aerobic oxidation of tertiary anilines, including
tetrahydroisoquinolines, to form reactive iminium ion intermediates that undergo Mannich …

The direct γ-carbon functionalization of α, β-unsaturated esters via N-Heterocyclic Carbene
(NHC) catalysis is disclosed. This catalytically generated nucleophilic γ-carbon undergoes …

Recent progress in the field of catalytic, enantioselective vinylogous Michael reactions of
latent dienolates is described which furnish optically highly enriched chiral 1, 7-dioxo …

In spite of the many catalytic methodologies available for the asymmetric functionalization of
carbonyl compounds at their α and β positions, little progress has been achieved in the …