Coinage metal nanoclusters (NCs), comprising a few to several hundred atoms, are prized
for their size‐dependent properties crucial in catalysis, sensing, and biomedicine. However …

Ligand-protected metal clusters possess hybrid properties that seamlessly combine an
inorganic core with an organic ligand shell, imparting them exceptional chemical flexibility …

Analyzing the molecular structure–photophysical property correlations of metal nanoclusters
to accomplish function-oriented photocatalysis could be challenging. Here, the selective …

The catalytic activity of ligand-protected metal nanoclusters is often hindered by the blocking
effect of surface ligands, necessitating the creation of more uncoordinated sites to enhance …

In recent years, the concept of Frustrated Lewis Pairs (FLPs), which consist of a combination
of Lewis acid (LA) and Lewis base (LB) active sites arranged in a suitable geometric …

The subvalent silver kernel represents the nascent state of silver cluster formation, yet the
growth mechanism has long been elusive. Herein, two silver nanoclusters (Ag30 and Ag34) …

The elucidation of hierarchical assembly structure of metal nanoclusters is of fundamental
importance in the context of bottom‐up fabrication and functionalization. While recent …

Achieving precise and controllable hierarchical self-assembly of functional nanoclusters
within crystal lattices to create distinct architectures is of immense significance, yet it creates …

We present the first example of an 99TcO4–anion entrapped within the cavity of a silver
cluster, revealing an unprecedented photoinduced charge transfer phenomenon.[Ag24 (C≡ …

Can the chemically synthesized nanoparticles act as nanodevices or nanomachines?
Herein, we demonstrated this feasibility. A novel nanocluster (ultrasmall nanoparticle) …