Recognition in the domain of molecular chirality: from noncovalent interactions to separation of enantiomers
It is not a coincidence that both chirality and noncovalent interactions are ubiquitous in
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …
Chiral recognition in separation sciences. Part I: Polysaccharide and cyclodextrin selectors
GKE Scriba - TrAC Trends in Analytical Chemistry, 2019 - Elsevier
The stereoselective recognition of chiral molecules is an important aspect in nature as the
basis of the interaction of chiral bioactive compounds with their target structures. In …
basis of the interaction of chiral bioactive compounds with their target structures. In …
Noncovalent interactions in high-performance liquid chromatography enantioseparations on polysaccharide-based chiral selectors
Designed more than thirty years ago in order to improve and maximize the discrimination
capability of native polysaccharides, cellulose-and amylose-based selectors have shown …
capability of native polysaccharides, cellulose-and amylose-based selectors have shown …
Enantioselective anion recognition by chiral halogen-bonding [2] rotaxanes
The application of chiral interlocked host molecules for discrimination of guest enantiomers
has been largely overlooked, which is surprising given their unique three-dimensional …
has been largely overlooked, which is surprising given their unique three-dimensional …
Modelling approaches for chiral chromatography on polysaccharide-based and macrocyclic antibiotic chiral selectors: A review
P De Gauquier, K Vanommeslaeghe… - Analytica Chimica …, 2022 - Elsevier
An overview of molecular modelling approaches, related to chiral separations on
polysaccharide-based and macrocyclic antibiotic chiral selectors, is presented. Both …
polysaccharide-based and macrocyclic antibiotic chiral selectors, is presented. Both …
Evidence for and evaluation of fluorine–tellurium chalcogen bonding
In the field of noncovalent interactions, chalcogen bonding (ChB) involving the tellurium
atom is currently attracting much attention in supramolecular chemistry and in catalysis …
atom is currently attracting much attention in supramolecular chemistry and in catalysis …
Engineering an alcohol dehydrogenase with enhanced activity and stereoselectivity toward diaryl ketones: reduction of steric hindrance and change of the …
K Wu, Z Yang, X Meng, R Chen, J Huang… - Catalysis Science & …, 2020 - pubs.rsc.org
Steric hindrance in the binding pocket of an alcohol dehydrogenase (ADH) has a great
impact on its activity and stereoselectivity simultaneously. Due to the subtle structural …
impact on its activity and stereoselectivity simultaneously. Due to the subtle structural …
The molecular bases of chiral recognition in 2-(benzylsulfinyl) benzamide enantioseparation
Liquid-phase chromatography on chiral stationary phase is still the most popular and
versatile technique to separate enantiomers, which is based on the ability of a chiral selector …
versatile technique to separate enantiomers, which is based on the ability of a chiral selector …
Stereoselective processes based on σ-hole interactions
The σ-hole interaction represents a noncovalent interaction between atoms with σ-hole (s)
on their surface (such as halogens and chalcogens) and negative sites. Over the last …
on their surface (such as halogens and chalcogens) and negative sites. Over the last …
Disubstituted ferrocenyl iodo-and chalcogenoalkynes as chiral halogen and chalcogen bond donors
Asymmetric catalysis based on halogen and chalcogen bonds (XB and ChB) is in its infancy,
and the search for new chiral XB and ChB donors represents a crucial step toward its …
and the search for new chiral XB and ChB donors represents a crucial step toward its …