o-Silylaryl Triflates: A Journey of Kobayashi Aryne Precursors
J Shi, L Li, Y Li - Chemical Reviews, 2021 - ACS Publications
Arynes are among the most active organic intermediates and have found numerous
applications in expeditious preparation of substituted arenes. In the past 20 years, chemists …
applications in expeditious preparation of substituted arenes. In the past 20 years, chemists …
Synthesis of nanographenes, starphenes, and sterically congested polyarenes by aryne cyclotrimerization
Conspectus In recent years, synthetic transformations based on aryne chemistry have
become particularly popular, mostly due to the spread of methods to generate these highly …
become particularly popular, mostly due to the spread of methods to generate these highly …
Expanded [2,1][n]Carbohelicenes with 15- and 17-Benzene Rings
M Toya, T Omine, F Ishiwari, A Saeki… - Journal of the …, 2023 - ACS Publications
Expanded carbohelicenes with structures fused to 15-and 17-benzene were successfully
synthesized. Establishing a new synthetic strategy is crucial to realize the development of …
synthesized. Establishing a new synthetic strategy is crucial to realize the development of …
On-surface synthesis of nanographenes and graphene nanoribbons on titanium dioxide
The formation of two types of nanographenes from custom designed and synthesized
molecular precursors has been achieved through thermally induced intramolecular …
molecular precursors has been achieved through thermally induced intramolecular …
Multiple helicenes featuring synthetic approaches and molecular structures
A Tsurusaki, K Kamikawa - Chemistry Letters, 2021 - academic.oup.com
Helicenes are attractive non-planar polycyclic aromatic hydrocarbons with unique optical
and electronic properties. In recent years, the chemistry of “multiple helicenes” with plural …
and electronic properties. In recent years, the chemistry of “multiple helicenes” with plural …
Fluorine-programmed nanozip** to tailored nanographenes on rutile TiO2 surfaces
The rational synthesis of nanographenes and carbon nanoribbons directly on nonmetallic
surfaces has been an elusive goal for a long time. We report that activation of the carbon (C) …
surfaces has been an elusive goal for a long time. We report that activation of the carbon (C) …
Overcrowded Triply Fused Carbo [7] helicene
A Artigas, F Rigoulet, M Giorgi… - Journal of the …, 2023 - ACS Publications
This paper presents the synthesis and comprehensive analysis of a highly contorted and
doubly negatively curved multihelicene compound, composed of three carbo [7] helicene …
doubly negatively curved multihelicene compound, composed of three carbo [7] helicene …
Stereoselective syntheses, structures, and properties of extremely distorted chiral nanographenes embedding hextuple helicenes
M Roy, V Berezhnaia, M Villa… - Angewandte Chemie …, 2020 - Wiley Online Library
We report a molecular design and concept using π‐system elongation and steric effects from
helicenes surrounding a triphenylene core toward stable chiral polycyclic aromatic …
helicenes surrounding a triphenylene core toward stable chiral polycyclic aromatic …
Scanning probe microscopy in probing low-dimensional carbon-based nanostructures and nanomaterials
C Zhang, Z Yi, W Xu - Materials Futures, 2022 - iopscience.iop.org
Carbon, as an indispensable chemical element on Earth, has diverse covalent bonding
ability, which enables construction of extensive pivotal carbon-based structures in multiple …
ability, which enables construction of extensive pivotal carbon-based structures in multiple …
On-surface synthesis with atomic hydrogen
Surface-assisted synthesis has become a powerful approach for generation of molecular
nanostructures, which could not be obtained via traditional solution chemistry. Nowadays …
nanostructures, which could not be obtained via traditional solution chemistry. Nowadays …