From stable radicals to thermally robust high-spin diradicals and triradicals

C Shu, Z Yang, A Rajca - Chemical Reviews, 2023‏ - ACS Publications
Stable radicals and thermally robust high-spin di-and triradicals have emerged as important
organic materials due to their promising applications in diverse fields. New fundamental …

Playing with organic radicals as building blocks for functional molecular materials

I Ratera, J Veciana - Chemical Society Reviews, 2012‏ - pubs.rsc.org
The literature has shown numerous contributions on the synthesis and physicochemical
properties of persistent organic radicals but there are a lesser number of reports about their …

Polymers for electronics and spintronics

P Bujak, I Kulszewicz-Bajer, M Zagorska… - Chemical Society …, 2013‏ - pubs.rsc.org
This critical review is devoted to semiconducting and high spin polymers which are of great
scientific interest in view of further development of the organic electronics and the emerging …

Organic mixed‐valence compounds: a playground for electrons and holes

A Heckmann, C Lambert - Angewandte Chemie International …, 2012‏ - Wiley Online Library
Mixed‐valence (MV) compounds are excellent model systems for the investigation of basic
electron‐transfer (ET) or charge‐transfer (CT) phenomena. These issues are important in …

Organic diradicals and polyradicals: from spin coupling to magnetism?

A Rajca - Chemical reviews, 1994‏ - ACS Publications
Diradicals and polyradicals are molecules that possess two or more weakly interacting
“unpaired” electrons, each formally associated with different atomic centers in a molecule …

[ספר][B] Dendrimers and dendrons: concepts, syntheses, applications

GR Newkome, CN Moorefield, F Vögtle, F Vögtle… - 2001‏ - Wiley Online Library
What's new in dendrimer research? Just as these fascinating giant molecules are continuing
to ramify, new perspectives and challenges continue to emerge. This bestseller on dendritic …

Organic and organometallic molecular magnetic materials—designer magnets

JS Miller, AJ Epstein - Angewandte Chemie International …, 1994‏ - Wiley Online Library
Magnets composed of molecular species or polymers and prepared by relatively low‐
temperature organic synthetic methodologies are a focus of contemporary materials science …

Electro-optical π-radicals: design advances, applications and future perspectives

P Murto, H Bronstein - Journal of Materials Chemistry C, 2022‏ - pubs.rsc.org
The unique open-shell electronic structure of neutral π-radicals has inspired research on
novel molecular materials for over a century. In recent years, rapid development in carbon …

Rational Design of an Air‐Stable, High‐Spin Diradical with Diazapyrene

Z Zhu, D Zhang, T **ao, YH Fang, X **ao… - Angewandte …, 2023‏ - Wiley Online Library
Stable carbon‐based polyradicals exhibiting strong spin‐spin coupling and slow
depolarization processes are particularly attractive functional materials. A new molecular …

Platform for high-spin molecules: A verdazyl-nitronyl nitroxide triradical with quartet ground state

EV Tretyakov, PV Petunin, SI Zhivetyeva… - Journal of the …, 2021‏ - ACS Publications
Thermally resistant air-stable organic triradicals with a quartet ground state and a large
energy gap between spin states are still unique compounds. In this work, we succeeded to …