The rise and current status of polaritonic photochemistry and photophysics

R Bhuyan, J Mony, O Kotov, GW Castellanos… - Chemical …, 2023 - ACS Publications
The interaction between molecular electronic transitions and electromagnetic fields can be
enlarged to the point where distinct hybrid light–matter states, polaritons, emerge. The …

Control, modulation, and analytical descriptions of vibrational strong coupling

BS Simpkins, AD Dunkelberger, I Vurgaftman - Chemical Reviews, 2023 - ACS Publications
Here, we review the design of optical cavities, transient and modulated responses, and
theoretical models relevant to vibrational strong coupling (VSC). While planar Fabry–Perot …

Molecular chemistry in cavity strong coupling

K Hirai, JA Hutchison, H Uji-i - Chemical Reviews, 2023 - ACS Publications
The coherent exchange of energy between materials and optical fields leads to strong light–
matter interactions and so-called polaritonic states with intriguing properties, halfway …

Molecular polaritonics: Chemical dynamics under strong light–matter coupling

TE Li, B Cui, JE Subotnik, A Nitzan - Annual review of physical …, 2022 - annualreviews.org
Chemical manifestations of strong light–matter coupling have recently been a subject of
intense experimental and theoretical studies. Here we review the present status of this field …

Two-dimensional electronic spectroscopy

E Fresch, FVA Camargo, Q Shen, CC Bellora… - Nature Reviews …, 2023 - nature.com
Two-dimensional electronic spectroscopy (2DES) is a popular technique that can track
ultrafast coherent and incoherent processes in real time. Since its development in the late …

Vibration-cavity polariton chemistry and dynamics

AD Dunkelberger, BS Simpkins… - Annual review of …, 2022 - annualreviews.org
Molecular polaritons result from light-matter coupling between optical resonances and
molecular electronic or vibrational transitions. When the coupling is strong enough, new …

Molecular polaritons for controlling chemistry with quantum optics

F Herrera, J Owrutsky - The Journal of chemical physics, 2020 - pubs.aip.org
This is a tutorial-style introduction to the field of molecular polaritons. We describe the basic
physical principles and consequences of strong light–matter coupling common to molecular …

Intermolecular vibrational energy transfer enabled by microcavity strong light–matter coupling

B **ang, RF Ribeiro, M Du, L Chen, Z Yang, J Wang… - Science, 2020 - science.org
Selective vibrational energy transfer between molecules in the liquid phase, a difficult
process hampered by weak intermolecular forces, is achieved through polaritons formed by …

Cavity-enabled enhancement of ultrafast intramolecular vibrational redistribution over pseudorotation

TT Chen, M Du, Z Yang, J Yuen-Zhou, W **ong - Science, 2022 - science.org
Vibrational strong coupling (VSC) between molecular vibrations and microcavity photons
yields a few polaritons (light-matter modes) and many dark modes (with negligible photonic …

Catalysis by dark states in vibropolaritonic chemistry

M Du, J Yuen-Zhou - Physical Review Letters, 2022 - APS
Collective strong coupling between a disordered ensemble of N localized molecular
vibrations and a resonant optical cavity mode gives rise to two polariton and N-1≫ 2 dark …