This article surveys the empirical information which originated both by laboratory
experiments and by computational simulations, and expands previous understanding of the …

To gain an understanding of the substitution effect on the unimolecular reaction rate
coefficients for Criegee intermediates (CIs), we performed ab initio calculations for CH2OO …

The Butler–Volmer (BV) equation links the current flux crossing an electrochemical interface
to the electric potential drop across it with the assumption of Arrhenius kinetics and the …

An analysis was carried out on the thermal dissociation of selected inorganic salts according
to Transition-State Theory (TST). For this purpose, two possibilities were compared in the …

Oxidation is an attractive treatment method to effectively remove organic contaminants in
water. In this study, degradation of 30 organic compounds in different oxidation systems was …

Kramers escape rate in the overdamped systems is restudied for the power-law distribution.
By using the mean first passage time, we derive the escape rate with the power-law …

Sets of Arrhenius parameters, determined according to known different equations for
dynamic conditions, in the vast majority form the Kinetic Compensation Effect (KCE) …

The collision theory for power-law distributions and the generalized reaction rate coefficient
are studied when reactions take place in nonequilibrium systems with power-law …

Kinetics and thermodynamics are largely disconnected in current theories because
Arrhenius activation energies (E a) have strictly no influence on equilibrium distributions. A …

The rate coefficient formulae of unimolecular reactions are generalized to the systems with
the power-law distributions based on nonextensive statistics, and the power-law rate …