Exploring actinide materials through synchrotron radiation techniques

WQ Shi, LY Yuan, CZ Wang, L Wang, L Mei… - Advanced …, 2014 - Wiley Online Library
Synchrotron radiation (SR) based techniques have been utilized with increasing frequency
in the past decade to explore the brilliant and challenging sciences of actinide‐based …

Colloid-borne forms of tetravalent actinides: a brief review

H Zänker, C Hennig - Journal of contaminant hydrology, 2014 - Elsevier
Abstract Tetravalent actinides, An (IV), are usually assumed to be little mobile in near-neutral
environmental waters because of their low solubility. However, there are certain …

Transformation of 2-line ferrihydrite to goethite at alkaline pH

FE Furcas, B Lothenbach, S Mundra… - Environmental …, 2023 - ACS Publications
The transformation of 2-line ferrihydrite to goethite from supersaturated solutions at alkaline
pH≥ 13.0 was studied using a combination of benchtop and advanced synchrotron …

Fe (III) uptake by calcium silicate hydrates

A Mancini, E Wieland, G Geng, R Dähn, J Skibsted… - Applied …, 2020 - Elsevier
Wet chemistry and spectroscopic investigations were conducted to study Fe (III) uptake by
calcium silicate hydrate (C–S–H) at different Ca/Si ratios. Wet chemistry experiments were …

Effect of ISA and chloride on the uptake of niobium (V) by hardened cement paste and CSH phases: Quantitative description and mechanistic understanding

Y Jo, N Çevirim-Papaioannou, K Franke, M Fuss… - Cement and Concrete …, 2023 - Elsevier
The uptake of niobium by hardened cement paste (HCP) and calcium silicate hydrate (CSH)
phases was investigated with 93 Nb and 95 Nb (t 1/2= 35.0 days). Structural materials used …

Systematic XAS study on the reduction and uptake of Tc by magnetite and mackinawite

E Yalçıntaş, AC Scheinost, X Gaona, M Altmaier - Dalton Transactions, 2016 - pubs.rsc.org
The mechanisms for the reduction and uptake of Tc by magnetite (Fe3O4) and mackinawite
(FeS) are investigated using X-ray absorption spectroscopy (XANES and EXAFS), in …

Fe (II) interaction with cement phases: Method development, wet chemical studies and X-ray absorption spectroscopy

A Mancini, E Wieland, G Geng, B Lothenbach… - Journal of colloid and …, 2021 - Elsevier
Fe (II) interaction with cement phases was studied by means of co-precipitation and sorption
experiments in combination with X-ray absorption fine structure (XAFS) spectroscopy …

Plutonium retention in the isosaccharinate–cement system

A Tasi, X Gaona, T Rabung, D Fellhauer, J Rothe… - Applied …, 2021 - Elsevier
Uptake of plutonium by Portland cement in degradation stage II was investigated in the
presence of α-D-isosaccharinic acid (ISA) under reducing conditions set by hydroquinone …

Effect of Ca (II) on U (VI) and Np (VI) retention on Ca-bentonite and clay minerals at hyperalkaline conditions-New insights from batch sorption experiments and …

T Philipp, N Huittinen, SSA Azzam, R Stohr… - Science of The Total …, 2022 - Elsevier
In deep geological repositories for radioactive waste, interactions of radionuclides with
mineral surfaces occur under complex geochemical conditions involving complex solution …

[HTML][HTML] U (VI) behaviour in hyperalkaline calcite systems

KF Smith, ND Bryan, AN Swinburne, P Bots… - … et Cosmochimica Acta, 2015 - Elsevier
The behaviour of U (VI) in hyperalkaline fluid/calcite systems was studied over a range of U
(VI) concentrations (5.27× 10− 5 μM to 42.0 μM) and in two high pH systems, young and old …