NIR‐Circularly Polarized Luminescence from Chiral Complexes of Lanthanides and d‐Metals

OG Willis, F Zinna, L Di Bari - … Chemie International Edition, 2023 - Wiley Online Library
In recent years, circularly polarized luminescence (CPL) has witnessed a renaissance, due
to the increased popularity of CPL as a spectroscopic technique and greater accessibility to …

Circularly polarized luminescence of lanthanide complexes: From isolated individuals, discrete oligomers, to hierarchical assemblies

Y Zhong, Z Wu, Y Zhang, B Dong, X Bai - InfoMat, 2023 - Wiley Online Library
Circularly polarized luminescence (CPL) is the emission featured spatial orientation
equivalent to circular dichroism. Owning to the unique magnetic dipole‐allowed but electric …

Strong circularly polarized luminescence at 1550 nm from enantiopure molecular erbium complexes

NFM Mukthar, ND Schley, G Ung - Journal of the American …, 2022 - ACS Publications
Circularly polarized luminescence (CPL) in two subregions of the near-infrared (NIR) has
been achieved. By leveraging the rigidity and diminishing detrimental vibrations of the …

Multifunctional Helicene‐Based Ytterbium Coordination Polymer Displaying Circularly Polarized Luminescence, Slow Magnetic Relaxation and Room Temperature …

K Dhbaibi, M Grasser, H Douib, V Dorcet… - Angewandte …, 2023 - Wiley Online Library
The combination of physical properties sensitive to molecular chirality in a single system
allows the observation of fascinating phenomena such as magneto‐chiral dichroism (MChD) …

Efficient 1400–1600 nm circularly polarized luminescence from a tuned Chiral erbium complex

OG Willis, F Petri, G Pescitelli, A Pucci… - Angewandte Chemie …, 2022 - Wiley Online Library
Novel chiral Er complexes based on both enantiomers of extended iPrPyBox (2, 6‐Bis [4‐
isopropyl‐4, 5‐dihydrooxazol‐2‐yl)] pyridine) show strong near‐infrared circularly polarized …

Intense 1400–1600 nm circularly polarised luminescence from homo-and heteroleptic chiral erbium complexes

OG Willis, A Pucci, E Cavalli, F Zinna… - Journal of Materials …, 2023 - pubs.rsc.org
Efficient near-infrared circularly polarised luminescence (CPL) between 1400 and 1600 nm
of four enantiomer pairs of homo-and heteroleptic complexes has been successfully …

Circularly polarized luminescence in the one-dimensional assembly of binaphtyl-based Yb (III) single-molecule magnets

CA Mattei, V Montigaud, B Lefeuvre, V Dorcet… - Journal of Materials …, 2023 - pubs.rsc.org
Lanthanide ions have attracted great interest owing to their optical and magnetic properties.
Single-molecule magnet (SMM) behavior has been a fascinating science for thirty years …

Vanol‐Supported Lanthanide Complexes for Strong Circularly Polarized Luminescence at 1550 nm

JA Adewuyi, ND Schley, G Ung - Chemistry–A European …, 2023 - Wiley Online Library
Strong circularly polarized luminescence (CPL) at 1550 nm is reported for lanthanide
complexes supported by Vanol; these are the first examples of coordination of Vanol to …

Impact of the experimental bandwidth on circularly polarized luminescence measurements of lanthanide complexes: the case of erbium (III)

A Sickinger, B Baguenard… - Journal of Materials …, 2024 - pubs.rsc.org
This article outlines the synthesis and comprehensive characterization of a pair of Er (III)
enantiomers with controlled helicity. These complexes exhibit a near-infrared circularly …

Circularly polarized luminescence and coordination geometries in mononuclear lanthanide (III) complexes

L Llanos, P Cancino, P Mella, P Fuentealba… - Coordination Chemistry …, 2024 - Elsevier
The interest in chirality crosses many research areas in chemistry, physics, materials, and
life sciences. Besides the fundamental importance of chiral recognition in biological …