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Photons or electrons? A critical comparison of electrochemistry and photoredox catalysis for organic synthesis
Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …
Visible-light induced direct C (sp3)-H functionalization: recent advances and future prospects
The direct activation of inert saturated C–H bonds for selective functionalization has long
been a significant challenge in organic synthesis. The past few decades have witnessed the …
been a significant challenge in organic synthesis. The past few decades have witnessed the …
Green chemistry: electrochemical organic transformations via paired electrolysis
Paired electrolysis is highly valuable from the viewpoint of efficiency as well as atom and
energy economies. In order to optimize the latter two for chemical reactions, the …
energy economies. In order to optimize the latter two for chemical reactions, the …
Asymmetric-waveform alternating current-promoted silver catalysis for C–H phosphorylation
L Zeng, Y Jiao, W Yan, Y Wu, S Wang, P Wang… - Nature …, 2023 - nature.com
Preventing metal deposition by cathodic reduction is a formidable challenge during
transition-metal-catalysed electrosynthesis under direct current (dc) electrolysis conditions …
transition-metal-catalysed electrosynthesis under direct current (dc) electrolysis conditions …
Synthesis of P-stereogenic cyclicphosphinic amides via electrochemically enabled cobalt-catalyzed enantioselective C–H annulation
T Liu, W Zhang, C Xu, Z Xu, D Song, W Qian, G Lu… - Green …, 2023 - pubs.rsc.org
The development of an electrochemical process method for the synthesis of P-chiral
phosphine derivatives poses a considerable challenge. Here, we present an electricity …
phosphine derivatives poses a considerable challenge. Here, we present an electricity …
Photochemical and electrochemical strategies towards benzylic C− H functionalization: a recent update
Transition metal‐catalysed processes have been widely used for the functionalization of
inert C− H bonds. Strategies for the functionalization of the benzylic C− H position having a …
inert C− H bonds. Strategies for the functionalization of the benzylic C− H position having a …
Electrochemical dearomative spirocyclization
N Li, Z Shi, WZ Wang, Y Yuan… - Chemistry–An Asian …, 2023 - Wiley Online Library
Electrochemical dearomative spirocyclization serves as a green and sustainable approach
to convert the flat, two‐dimension aromatic feedstock into the value‐added three‐dimension …
to convert the flat, two‐dimension aromatic feedstock into the value‐added three‐dimension …
Electrohalogenation of organic compounds
MR Scheide, CR Nicoleti, GM Martins… - Organic & Biomolecular …, 2021 - pubs.rsc.org
Herein, we present an overview of recent advances in the electrochemical halogenation of
organic compounds. Halogen-containing compounds are essential building blocks for post …
organic compounds. Halogen-containing compounds are essential building blocks for post …
Electrochemical CH halogenations of enaminones and electron-rich arenes with sodium halide (NaX) as halogen source for the synthesis of 3-halochromones and …
Y Lin, J **, C Wang, JP Wan, Y Liu - The Journal of Organic …, 2021 - ACS Publications
Without employing an external oxidant, the simple synthesis of 3-halochromones and
various halogenated electron-rich arenes has been realized with electrode oxidation by …
various halogenated electron-rich arenes has been realized with electrode oxidation by …
Electrochemical Oxidative Halogenation of N-Aryl Alkynamides for the Synthesis of Spiro[4.5]trienones
K Yu, X Kong, J Yang, G Li, B Xu… - The Journal of Organic …, 2020 - ACS Publications
We developed a green method for the synthesis of spiro [4.5] trienones through an
electrochemical oxidative halocyclization with N-aryl alkynamides. This reaction was …
electrochemical oxidative halocyclization with N-aryl alkynamides. This reaction was …