Surface and interface coordination chemistry learned from model heterogeneous metal nanocatalysts: from atomically dispersed catalysts to atomically precise …

W **g, H Shen, R Qin, Q Wu, K Liu, N Zheng - Chemical Reviews, 2022 - ACS Publications
The surface and interface coordination structures of heterogeneous metal catalysts are
crucial to their catalytic performance. However, the complicated surface and interface …

Understanding ligand-protected noble metal nanoclusters at work

MF Matus, H Häkkinen - Nature Reviews Materials, 2023 - nature.com
Ligand-protected noble metal nanoclusters, commonly termed 'monolayer-protected metal
clusters'(MPCs), comprise a common set of structures with an inorganic core stabilized by an …

Recent developments in the investigation of driving forces for transforming coinage metal nanoclusters

X Zou, X Kang, M Zhu - Chemical Society Reviews, 2023 - pubs.rsc.org
Metal nanoclusters serve as an emerging class of modular nanomaterials. The
transformation of metal nanoclusters has been fully reflected in their studies from every …

Atomically precise alloy nanoclusters: syntheses, structures, and properties

X Kang, Y Li, M Zhu, R ** - Chemical Society Reviews, 2020 - pubs.rsc.org
Metal nanoclusters fill the gap between discrete atoms and plasmonic nanoparticles,
providing unique opportunities for investigating the quantum effects and precise structure …

Eight-Electron Superatomic Cu31 Nanocluster with Chiral Kernel and NIR-II Emission

T Jia, ZJ Guan, C Zhang, XZ Zhu, YX Chen… - Journal of the …, 2023 - ACS Publications
Owing to the inherent instability caused by the low Cu (I)/Cu (0) half-cell reduction potential,
Cu (0)-containing copper nanoclusters are quite uncommon in comparison to their Ag and …

Suppression of kernel vibrations by layer-by-layer ligand engineering boosts photoluminescence efficiency of gold nanoclusters

Y Zhong, J Zhang, T Li, W Xu, Q Yao, M Lu… - Nature …, 2023 - nature.com
The restriction of structural vibration has assumed great importance in attaining bright
emission of luminescent metal nanoclusters (NCs), where tremendous efforts are devoted to …

Electrostatic co-assembly of nanoparticles with oppositely charged small molecules into static and dynamic superstructures

T Bian, A Gardin, J Gemen, L Houben, C Perego… - Nature …, 2021 - nature.com
Coulombic interactions can be used to assemble charged nanoparticles into higher-order
structures, but the process requires oppositely charged partners that are similarly sized. The …

Electrochemical NO3 Reduction Catalyzed by Atomically Precise Ag30Pd4 Bimetallic Nanocluster: Synergistic Catalysis or Tandem Catalysis?

L Qin, F Sun, Z Gong, G Ma, Y Chen, Q Tang, L Qiao… - ACS …, 2023 - ACS Publications
Electrochemically converting NO3–compounds into ammonia represents a sustainable route
to remove industrial pollutants in wastewater and produce valuable chemicals. Bimetallic …

Shell engineering to achieve modification and assembly of atomically-precise silver clusters

Y **, C Zhang, XY Dong, SQ Zang… - Chemical Society …, 2021 - pubs.rsc.org
Continuing research on the preparation and structural determination of monolayer-protected
silver clusters has been performed. The compounds include mixed-valence Ag0/1+ clusters …

Endohedrally doped cage clusters

J Zhao, Q Du, S Zhou, V Kumar - Chemical Reviews, 2020 - ACS Publications
The discovery of carbon fullerene cages and their solids opened a new avenue to build
materials from stable cage clusters as “artificial atoms” or “superatoms” instead of atoms …