Ceria-based model catalysts: fundamental studies on the importance of the metal–ceria interface in CO oxidation, the water–gas shift, CO 2 hydrogenation, and …

JA Rodriguez, DC Grinter, Z Liu… - Chemical Society …, 2017 - pubs.rsc.org
Model metal/ceria and ceria/metal catalysts have been shown to be excellent systems for
studying fundamental phenomena linked to the operation of technical catalysts. In the last …

Chemistry with methane: concepts rather than recipes

H Schwarz - Angewandte Chemie International Edition, 2011 - Wiley Online Library
Four seemingly simple transformations related to the chemistry of methane will be
addressed from mechanistic and conceptual points of view: 1) metal‐mediated …

IR spectroscopic investigations of chemical and photochemical reactions on metal oxides: bridging the materials gap

Y Wang, C Wöll - Chemical Society Reviews, 2017 - pubs.rsc.org
In this review, we highlight recent progress (2008–2016) in infrared reflection absorption
spectroscopy (IRRAS) studies on oxide powders achieved by using different types of metal …

Surface chemistry and catalysis of oxide model catalysts from single crystals to nanocrystals

S Chen, F **ong, W Huang - Surface Science Reports, 2019 - Elsevier
Fundamental understandings of surface chemistry and catalysis of solid catalysts are of
great importance for the developments of efficient catalysts and corresponding catalytic …

MnOx-decorated VOx/CeO2 catalysts with preferentially exposed {110} facets for selective catalytic reduction of NOx by NH3

X Wu, X Yu, Z Huang, H Shen, G **g - Applied Catalysis B: Environmental, 2020 - Elsevier
Highly dispersed MnO x-decorated VO x/CeO 2 catalysts with preferentially exposed {110}
facets were chosen to improve the low-temperature (200− 250° C) NH 3-SCR activity. In this …

Well-ordered transition metal oxide layers in model catalysis–a series of case studies

H Kuhlenbeck, S Shaikhutdinov, HJ Freund - Chemical reviews, 2013 - ACS Publications
The development of surface science of solid metal surfaces during the last 50 years has
been intimately connected with heterogeneous catalysis and culminated in the Nobel prize …

Partial oxidation of ethanol on vanadia catalysts on supporting oxides with different redox properties compared to propane

B Beck, M Harth, NG Hamilton, C Carrero, JJ Uhlrich… - Journal of …, 2012 - Elsevier
The influence of the support material of vanadia catalysts on the reaction rate, activation
energies, and defect formation enthalpies was investigated for the oxidative …

Engineered nanomaterials: From their properties and applications, to their toxicity towards marine bivalves in a changing environment

L De Marchi, F Coppola, AMVM Soares, C Pretti… - Environmental …, 2019 - Elsevier
As a consequence of their unique characteristics, the use of Engineered Nanomaterials
(ENMs) is rapidly increasing in industrial, agricultural products, as well as in environmental …

Model studies in heterogeneous catalysis

HJ Freund - Chemistry–A European Journal, 2010 - Wiley Online Library
I review a concept that models heterogeneous catalysis based on a surface‐science
approach. It is shown that models catching part of the complexity of the real system, which is …

Heterometallic CeIV/ VV Oxo Clusters with Adjustable Catalytic Reactivities

X Wang, K Brunson, H **e, I Colliard… - Journal of the …, 2021 - ACS Publications
Heterometallic CeIV/M oxo clusters are underexplored yet and can benefit from synergistic
properties from combining cerium and other metal cations to produce efficient redox …