TURBOMOLE: Today and tomorrow

YJ Franzke, C Holzer, JH Andersen… - Journal of chemical …, 2023 - ACS Publications
TURBOMOLE is a highly optimized software suite for large-scale quantum-chemical and
materials science simulations of molecules, clusters, extended systems, and periodic solids …

Delocalization error: The greatest outstanding challenge in density‐functional theory

KR Bryenton, AA Adeleke, SG Dale… - Wiley Interdisciplinary …, 2023 - Wiley Online Library
Every day, density‐functional theory (DFT) is routinely applied to computational modeling of
molecules and materials with the expectation of high accuracy. However, in certain …

Subsurface A-site vacancy activates lattice oxygen in perovskite ferrites for methane anaerobic oxidation to syngas

J He, T Wang, X Bi, Y Tian, C Huang, W Xu… - Nature …, 2024 - nature.com
Tuning the oxygen activity in perovskite oxides (ABO3) is promising to surmount the trade-off
between activity and selectivity in redox reactions. However, this remains challenging due to …

Improving the accuracy of atomistic simulations of the electrochemical interface

R Sundararaman, D Vigil-Fowler, K Schwarz - Chemical reviews, 2022 - ACS Publications
Atomistic simulation of the electrochemical double layer is an ambitious undertaking,
requiring quantum mechanical description of electrons, phase space sampling of liquid …

Improving results by improving densities: Density-corrected density functional theory

E Sim, S Song, S Vuckovic, K Burke - Journal of the American …, 2022 - ACS Publications
Density functional theory (DFT) calculations have become widespread in both chemistry and
materials, because they usually provide useful accuracy at much lower computational cost …

[HTML][HTML] High-throughput predictions of metal–organic framework electronic properties: theoretical challenges, graph neural networks, and data exploration

AS Rosen, V Fung, P Huck, CT O'Donnell… - npj Computational …, 2022 - nature.com
With the goal of accelerating the design and discovery of metal–organic frameworks (MOFs)
for electronic, optoelectronic, and energy storage applications, we present a dataset of …

Rapid interlayer charge separation and extended carrier lifetimes due to spontaneous symmetry breaking in organic and mixed organic–inorganic Dion–Jacobson …

R Shi, R Long, WH Fang… - Journal of the American …, 2023 - ACS Publications
Promising alternatives to three-dimensional perovskites, two-dimensional (2D) layered
metal halide perovskites have proven their potential in optoelectronic applications due to …

Toward the next generation of density functionals: Esca** the zero-sum game by using the exact-exchange energy density

M Kaupp, A Wodyński, AV Arbuznikov… - Accounts of Chemical …, 2024 - ACS Publications
Conspectus Kohn–Sham density functional theory (KS DFT) is arguably the most widely
applied electronic-structure method with tens of thousands of publications each year in a …

Density functional theory and molecular dynamics simulations for resistive switching research

MA Villena, O Kaya, U Schwingenschlögl… - Materials Science and …, 2024 - Elsevier
Resistive switching (RS) devices, often referred to as memristors, have exhibited interesting
electronic performance that could be useful to enhance the capabilities of multiple types of …

High-entropy materials for electrocatalytic applications: a review of first principles modeling and simulations

W Huo, S Wang, FJ Dominguez-Gutierrez… - Materials Research …, 2023 - Taylor & Francis
High-entropy materials, for both complexity in structure and superiority in performance, have
been widely confirmed to be one possible kind of advanced electrocatalyst. Significant …