Metal complex catalysis in the synthesis of spirocarbocycles
VA D'yakonov, OA Trapeznikova, A de Meijere… - Chemical …, 2014 - ACS Publications
Spirans contain at least two rings, which share one carbon atom called the spirocarbon
atom. 1 Synthetic and natural spirocarbocycles attract the attention of organic chemists due …
atom. 1 Synthetic and natural spirocarbocycles attract the attention of organic chemists due …
[HTML][HTML] Recent advances in transition-metal-catalyzed intermolecular carbomagnesiation and carbozincation
K Murakami, H Yorimitsu - Beilstein journal of organic …, 2013 - beilstein-journals.org
Carbomagnesiation and carbozincation reactions are efficient and direct routes to prepare
complex and stereodefined organomagnesium and organozinc reagents. However, carbon …
complex and stereodefined organomagnesium and organozinc reagents. However, carbon …
The facile synthesis of the 5Z, 9Z-dienoic acids and their topoisomerase I inhibitory activity
An original, effective approach to the synthesis of natural and synthetic 5Z, 9Z-dienoic acids
in high yields (61–67%) and with high selectivity (> 98%) was developed. The approach is …
in high yields (61–67%) and with high selectivity (> 98%) was developed. The approach is …
Advances in the chemistry of natural and semisynthetic topoisomerase I/II inhibitors
The search for new, effective, and low-toxic anticancer agents is one of the most important
tasks of modern medicinal chemistry. In general, the solution to this problem comes down to …
tasks of modern medicinal chemistry. In general, the solution to this problem comes down to …
Metallacomplex catalysis in the synthesis of regular isoprenoids
This brief review covers and systematizes the key results acquired using metal complex
catalysts in both fundamental and applied research aimed at the development of methods …
catalysts in both fundamental and applied research aimed at the development of methods …
Natural compounds with bis-methylene-interrupted Z-double bonds: plant sources, strategies of total synthesis, biological activity, and perspectives
The review summarizes data on natural compounds including higher carboxylic acids,
acetogenins, lembehynes, and insect pheromones containing bis-methylene-interrupted Z …
acetogenins, lembehynes, and insect pheromones containing bis-methylene-interrupted Z …
Natural Acetogenins, Chatenaytrienins-1,-2,-3 and-4, Mitochondrial Potential Uncouplers and Autophagy Inducers—Promising Anticancer Agents
The present paper details the complete stereoselective synthesis of four natural
acetogenins, chatenaytrienins-1,-2,-3 and-4, previously isolated from the roots of fruit trees …
acetogenins, chatenaytrienins-1,-2,-3 and-4, previously isolated from the roots of fruit trees …
nZ,(n + 4)Z-Dienoic fatty acids: a new method for the synthesis and inhibitory action on topoisomerase I and IIα
An original, effective approach to the stereoselective method for the synthesis of higher
unsaturated acids containing a 1Z, 5Z-diene group in 61–75% yields and with> 98 …
unsaturated acids containing a 1Z, 5Z-diene group in 61–75% yields and with> 98 …
Novel organomagnesium reagents in synthesis. Catalytic cyclomagnesiation of allenes in the synthesis of N-, O-, and Si-substituted 1Z, 5Z-dienes
VA D'yakonov, AA Makarov, EK Makarova… - Tetrahedron, 2013 - Elsevier
An efficient method for the synthesis of valuable N-, O-, and Si-containing 1Z, 5Z-diene
compounds was developed. The method comprises Cp 2 TiCl 2-catalyzed homo-and cross …
compounds was developed. The method comprises Cp 2 TiCl 2-catalyzed homo-and cross …
Catalytic cyclometalation reaction of unsaturated compounds in synthesis of magnesa-and aluminacarbocycles
UM Dzhemilev, AG Ibragimov - Journal of Organometallic Chemistry, 2010 - Elsevier
The investigation results on design and application of the new catalytic cyclometalation
reaction of olefins, dienes, acetylenes and allenes with Al, Mg and halogen alkyls mediated …
reaction of olefins, dienes, acetylenes and allenes with Al, Mg and halogen alkyls mediated …