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The chemistry of heterocycles in the 21st century
VN Charushin, EV Verbitskiy, ON Chupakhin… - Uspekhi Khimii, 2024 - mathnet.ru
The chemistry of heterocyclic compounds has traditionally been and remains a bright area of
chemical science in Russia. This is due to the fact that many heterocycles find the widest …
chemical science in Russia. This is due to the fact that many heterocycles find the widest …
Proline Analogues
Within the canonical repertoire of the amino acid involved in protein biogenesis, proline
plays a unique role as an amino acid presenting a modified backbone rather than a side …
plays a unique role as an amino acid presenting a modified backbone rather than a side …
Visible-light-induced palladium-catalyzed selective defluoroarylation of trifluoromethylarenes with arylboronic acids
Selective functionalization of inactive C (sp3)–F bonds to prepare medicinally interesting
aryldifluoromethylated compounds remains challenging. One promising route is the …
aryldifluoromethylated compounds remains challenging. One promising route is the …
Cobalt-catalysed enantioselective C(sp3)–C(sp3) coupling
Abstract Enantioselective C (sp 3)–C (sp 3) coupling substantially impacts organic synthesis
but remains challenging. Cobalt has played an important role in the development of …
but remains challenging. Cobalt has played an important role in the development of …
Solid‐State Radical C− H Trifluoromethylation Reactions Using Ball Milling and Piezoelectric Materials
The application of piezoelectricity for the generation of trifluoromethyl (CF3) radicals is
reported together with the development of a method for the mechanochemical C− H …
reported together with the development of a method for the mechanochemical C− H …
Chemo‐, Stereo‐ and Regioselective Fluoroallylation/Annulation of Hydrazones with gem‐Difluorocyclopropanes via Tunable Palladium/NHC Catalysis
Defluorinative manipulation of polyfluorinated molecules has shown great promise due to its
granting of synthetic versatility to inert C− F bonds. The development of chemo‐, stereo‐and …
granting of synthetic versatility to inert C− F bonds. The development of chemo‐, stereo‐and …
Metal-free, visible-light driven α-C (sp 3)–H gem-difluoroallylation of glycine derivatives with trifluoromethyl alkenes and 1, 3-enynes
ZH Yuan, H **n, L Zhang, P Gao, X Yang, XH Duan… - Green …, 2023 - pubs.rsc.org
A metal free, visible-light driven α-C (sp3)–H gem-difluoroallylation of glycine derivatives
with trifluoromethyl alkenes and 1, 3-enynes is presented. This protocol features mild and …
with trifluoromethyl alkenes and 1, 3-enynes is presented. This protocol features mild and …
Electrochemical Trifluoromethylthiolation and Spirocyclization of Alkynes with AgSCF3: Access to SCF3-Containing Spiro[5,5]trienones
A novel and efficient strategy for trifluoromethylthiolation and dearomatization of activated
alkynes with stable and readily available AgSCF3 has been developed. Reported herein is …
alkynes with stable and readily available AgSCF3 has been developed. Reported herein is …
Palladium‐Catalyzed Defluorinative Alkylation of gem‐Difluorocyclopropanes: Switching Regioselectivity via Simple Hydrazones
Conventional approaches for Pd‐catalyzed ring‐opening cross‐couplings of gem‐
difluorocyclopropanes with nucleophiles predominantly deliver the β‐fluoroalkene scaffolds …
difluorocyclopropanes with nucleophiles predominantly deliver the β‐fluoroalkene scaffolds …
Desymmetrization of geminal difluoromethylenes using a palladium/copper/lithium ternary system for the stereodivergent synthesis of fluorinated amino acids
Y Luo, Y Ma, G Li, X Huo… - Angewandte Chemie …, 2023 - Wiley Online Library
Fluorinated amino acids and related peptides/proteins have been found widespread
applications in pharmaceutical and agricultural compounds. However, strategies for …
applications in pharmaceutical and agricultural compounds. However, strategies for …