Jahn–Teller (JT) distorted CuII-containing compounds often display interesting structural
and functional behaviour upon compression. We use high-pressure X-ray and neutron …

This work presents two isostructural Cu (I)-I 2-fluoropyrazine (Fpyz) luminescent and
semiconducting 2D coordination polymers (CPs). Hydrothermal synthesis allows the growth …

Clinoatacamite (γ-Cu2 (OH) 3Cl) possesses a geometrically frustrated kagome lattice for the
S= 1/2 antiferromagnetic spin system. Thus, it is deemed as the mother compound of many …

Van der Waals (vdW) magnets offer unique opportunities for exploring magnetism in the 2D
limit. Metal–organic magnets (MOM) are of particular interest as the functionalisation of …

Two coordination polymers,[M (5-hip)(H2O) 3] n (M= Cd2+ (1), Zn2+ (2), 5-hip= 5-
hydroxyisophthalic acid), have been synthesized under hydrothermal conditions. The crystal …

We investigate the cause of spatial superexchange anisotropy in a family of copper-based,
quasi-two-dimensional materials with very similar geometries. The compounds in this family …

A family of pyrazine-bridged, linear chain complexes of Cu (II) of the formula [CuL2 (H2O) 2
(pz)](ClO4) 2 [pz= pyrazine; L= n-methyl-2 (1H)-pyridone, n= 3 (1), 5 (2), and 6 (3)] has been …

Two new pyrazine-bridged, linear chain complexes of Cu (II) of formula [Cu (pzdo) 2 (H2O) 2
(pz)](A) 2· nH2O [pzdo= pyrazine-N, N′-dioxide; pz= pyrazine; A= BF4−(1), ClO4−(2)] have …

In order to study the influence of different solvent molecules on the proton conductivities of
MOFs,{[Zn (pyeb) 2](DMF)(H2O)} n (1)(PyebH= 4-[2-(4-pyridyl) vinyl)]-benzoic acid, DMF …

High-pressure electrides (HPEs) represent a unique class of materials characterized by the
localization of electrons in non-bonding interstitial regions, distinct from typical atom-atom …