Structure and dynamics of monohydroxy alcohols—Milestones towards their microscopic understanding, 100 years after Debye

R Böhmer, C Gainaru, R Richert - Physics Reports, 2014 - Elsevier
In 1913 Debye devised a relaxation model for application to the dielectric properties of water
and alcohols. These hydrogen-bonded liquids continue to be studied extensively because …

The grotthuss mechanism

N Agmon - Chemical Physics Letters, 1995 - Elsevier
Suggested mechanisms for proton mobility are confronted with experimental findings and
quantum mechanical calculations, indicating that no model is consistent with the existing …

Effect of environment on hydrogen bond dynamics in liquid water

A Luzar, D Chandler - Physical review letters, 1996 - APS
In a series of molecular dynamics calculations we simulate the dynamics of forming and
breaking a hydrogen bond in liquid water at room temperature. We show that this dynamics …

Structure and hydrogen bond dynamics of water–dimethyl sulfoxide mixtures by computer simulations

A Luzar, D Chandler - The Journal of chemical physics, 1993 - pubs.aip.org
We have used two different force field models to study concentrated dimethyl sulfoxide
(DMSO)-water solutions by molecular dynamics. The results of these simulations are shown …

Experimental determination of the nature of diffusive motions of water molecules at low temperatures

J Teixeira, MC Bellissent-Funel, SH Chen, AJ Dianoux - Physical Review A, 1985 - APS
Extensive and high-quality quasi-elastic incoherent neutron scattering data were obtained
for water in the temperature range extending from room temperature down to-20 C in the …

Dielectric spectra of some common solvents in the microwave region. Water and lower alcohols

J Barthel, K Bachhuber, R Buchner… - Chemical physics letters, 1990 - Elsevier
Precise complex permittivity spectra of the hydrogen-bonding liquids water, methanol,
ethanol, 1-propanol, and 2-propanol have been determined in the frequency range 0.95-89 …

Low-frequency spetroscopic studies of interactions in liquids

OF Nielsen - Annual Reports Section" C"(Physical Chemistry), 1993 - pubs.rsc.org
Vibrational spectroscopy has been an important tool in studies of intermolecular interactions
in dense phases, Four excellent contributions on this subject have previously been reported …

The dielectric properties of water in its different states of interaction

U Kaatze - Journal of solution chemistry, 1997 - Springer
A tutorial on dielectric (relaxation) spectrometry of liquids is given in this article. Some
methods of measuring complex (electric) permittivity spectra are briefly described. Results …

Fast and slow dynamics of hydrogen bonds in liquid water

FW Starr, JK Nielsen, HE Stanley - Physical Review Letters, 1999 - APS
We study hydrogen-bond dynamics in liquid water at low temperatures using molecular
dynamics simulations, and find results supporting the hypothesized continuity of dynamic …

Tetrahedral displacement: The molecular mechanism behind the Debye relaxation in water

N Agmon - The Journal of Physical Chemistry, 1996 - ACS Publications
The arguments for and against a single-molecule rotation mechanism for dielectric
relaxation of water are surveyed. It is concluded that two distinct molecular mechanisms are …